venerdì 9 novembre 2007

Large Hadron Collider Ready To Go


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ScienceDaily (Nov. 9, 2007) — CERN Director General Robert Aymar sealed the last interconnect in the world’s largest cryogenic system, the Large Hadron Collider (LHC). This is the latest milestone in commissioning the LHC, the world’s most powerful particle accelerator.
The LHC’s cryogenic system has the task of cooling some 36 800 tonnes of material to a temperature of just 1.9 degrees above absolute zero (–271.3°C), colder than outer space. To do this, over 10 000 tonnes of liquid nitrogen and 130 tonnes of liquid helium will be deployed through a cryogenic system including over 40 000 leak-tight welds. Today’s ceremony marks the end of a two year programme of work to connect all the main dipole and quadrupole magnets in the LHC. This complex task included both electrical and fluid connections.
“This is a huge accomplishment,” said Lyn Evans, LHC project leader. “Now that it is done, we can concentrate on getting the machine cold and ready for physics.”
The LHC is a circular machine, 27 kilometres around and divided into eight sectors, each of which can be cooled down to its operating temperature of 1.9 degrees above absolute zero and powered-up individually. One sector was cooled down, powered and warmed up in the first half of 2007. This was an important learning process, allowing subsequent sectors to be tested more quickly.
“Over the coming months, we’ll be cooling down the remaining sectors,” said Evans. “Five sectors will be cooling by the end of 2007, with the remaining three joining them early next year.”
If all goes well, the first beams could be injected into the LHC in May 2008, and circulating beams established by June or July. With a project of this scale and complexity, however, the transition from construction to operation is a lengthy process.
“There is no big red button, and there are inevitably hurdles to be overcome as we bring the LHC into operation,” said Aymar, “Every part of the system has to be brought on stream carefully, with each sub-system and component tested and repaired if necessary.”
“There have been no show-stoppers so far,” added Evans. “For a machine of this complexity, things are going remarkably smoothly and we’re all looking forward to doing physics with the LHC next summer. If for any reason we have to warm up a sector, though,” he cautioned, “we’ll be looking at the end of summer rather than the beginning.”
Adapted from materials provided by CERN.

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martedì 6 novembre 2007

Heavier Hydrogen On The Atomic Scale Reduces Friction


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ScienceDaily (Nov. 6, 2007) — Scientists may be one step closer to understanding the atomic forces that cause friction, thanks to a recently published study by researchers from the University of Pennsylvania, the University of Houston and the U.S. Department of Energy's Argonne National Laboratory.
The research, led by Robert Carpick of the University of Pennsylvania, found a significant difference in friction exhibited by diamond surfaces that had been coated with different isotopes of hydrogen and then rubbed against a small carbon-coated tip.
Scientists lack a comprehensive model of friction on the nanoscale and only generally grasp its atomic-level causes, which range from local chemical reactions to electronic interactions to phononic, or vibrational, resonances.
To investigate the latter, Argonne scientist Anirudha Sumant and his colleagues used single-crystal diamond surfaces coated with layers of either atomic hydrogen or deuterium, a hydrogen atom with an extra neutron. The deuterium-terminated diamonds had lower friction forces because of their lower vibrational frequencies, an observation that Sumant attributed to that isotope's larger mass. They have also observed same trend on a silicon substrate, which is structurally similar to that of diamond.
Previous attempts to make hydrogen-terminated diamond surfaces relied on the use of plasmas, which tended to etch the material.
"When you're looking at such a small isotopic effect, an objectively tiny change in the mass, you have to be absolutely sure that there are no other complicating effects caused by chemical or electronic interferences or by small topographic variations," Sumant said. "The nanoscale roughening of the diamond surface from the ion bombardment during the hydrogen or deuterium termination process, even though it was at very low level, remained one of our principal concerns."
Sumant and his collaborators had looked at a number of other ways to try to avoid etching, even going to such lengths as to soak the films in olive oil before applying the hydrogen layers. However, no method had provided a smooth, defect-free hydrogen layer with good coverage that would avoid generating background noise, he said.
However, while performing work at the University of Wisconsin-Madison, Sumant developed a system for depositing diamond thin films. The technique, called hot filament chemical vapor deposition, involves the heating of a tungsten filament (like those found in incandescent light bulbs) to over 2000 degrees Celsius.
If the diamond film is exposed to a flow of molecular hydrogen while sitting within a centimeter of the hot filament, the heat will cause the molecular hydrogen to break down into atomic hydrogen, which will react with the film's surface to create a perfectly smooth layer. Since this method does not require the use of plasma, there is no danger of ion-induced etching.
"We've proved that this is a gentler method of terminating a diamond surface," Sumant said.
Sumant said that he hopes to use the knowledge gained from the experiment to eventually discover a way to manipulate the friction of surfaces on the atomic level. Such a result would prove immensely valuable to the development of nanoelectromechanical systems, or NEMS, based on diamonds, one of Sumant's primary research interests at Argonne's Center for Nanoscale Materials.
The paper, "Nanoscale Friction Varied by Isotopic Shifting of Surface Vibrational Frequencies," appears in the November 2 issue of Science.
The research was supported by the National Science Foundation, an NSF Graduate Research Fellowship, the Air Force Office of Scientific Research and the Department of Energy's Office of Science, Office of Basic Energy Sciences.
Adapted from materials provided by DOE/Argonne National Laboratory.

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lunedì 5 novembre 2007

How Electrons 'Gain Weight' In Metal Compounds Near Absolute Zero


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ScienceDaily (Nov. 5, 2007) — Rutgers University physicists have performed computer simulations that show how electrons become one thousand times more massive in certain metal compounds when cooled to temperatures near absolute zero -- the point where all motion ceases. The models may provide new clues as to how superconductivity works and how new superconducting materials could be fabricated.
In a paper posted to Science Express, a Web site of research reports slated for upcoming print editions of Science, the researchers describe how electrons interact with other particles in these compounds to morph into what physicists call a fluid of "heavy quasiparticles" or a "heavy fermion fluid." While this effect has been previously observed in some materials, the Rutgers work employs new materials to provide a level of detail that has eluded scientists so far.
"In this paper, we essentially track the fate of electrons as we lower the temperature," said Gabi Kotliar, Board of Governors Professor of Physics in the School of Arts and Sciences. "Experimental physicists may have seen different aspects of this behavior, or they may have seen behaviors they did not understand. Our calculations reconcile what they've seen."
The Rutgers researchers based their models on experiments using a new metallic crystalline compound made of the elements cerium, indium and iridium. This and similar compounds that substitute cobalt and rhodium for iridium are excellent test beds for observing heavy electron behavior.
Earlier investigations used high-temperature superconducting materials called cuprates, which failed to give physicists a clear view of electron behavior because of disorders in the crystalline structure caused by doping. The new cerium-based compounds are simpler to study because they are free of dopants.
"The new compounds are for us what fruit flies are for genetics researchers," said Kristjan Haule, assistant professor of physics and astronomy. "Fruit flies are easy to breed and have a simple gene makeup that's easy to change. Likewise, these compounds are easy to make, structurally straightforward and adjustable, giving us a clearer view into the many properties of matter that arise at low temperatures. For example, we can use a magnetic field to kill superconductivity and examine the state of matter from which superconductivity arose."
These compounds are examples of strongly correlated materials, or materials with strongly interacting electrons, that can't be described by theories that treat electrons as largely independent entities. The terms "heavy quasiparticles" refers to how electrons interact with each other and, as a result of those interactions, form a new type of particle called a "quasiparticle."
In explaining how this effect appears at low temperatures and vanishes at higher ones, Haule noted that electrons in f-orbitals are tightly bound to cerium atoms at room temperature. But as the temperature drops, the electrons exhibit coherent behavior, or delocalization from their atoms. At 50 degrees above absolute zero, or 50 degrees Kelvin, the researchers clearly observe quasiparticles as electrons interact with each other and other electrons in the metal known as conduction electrons.
The work done by Haule and his colleagues is in a branch of physics known as condensed matter physics, which deals with the physical properties of solid and liquid matter. Their models of heavy quasiparticles draw from Haule's earlier work merging two theories of atomic modeling, known as local density approximation and dynamical mean field theory, or LDA+DMFT.
Collaborating with Haule and Kotliar was Ji-Hoon Shim, a postdoctoral fellow. The National Science Foundation's Division of Materials Research and the Rutgers Center for Materials Theory supported their research. Shim received postdoctoral research funding from the Korean Research Foundation.
Adapted from materials provided by Rutgers University.

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Electron Spin Rotated With Electric Field


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ScienceDaily (Nov. 5, 2007) — Researchers at the Delft University of Technology's Kavli Institute of Nanoscience and the Foundation for Fundamental Research on Matter (FOM) have succeeded in controlling the spin of a single electron merely by using electric fields. This clears the way for a much simpler realization of the building blocks of a (future) super-fast quantum computer.
Controlling the spin of a single electron is essential if this spin is to be used as the building block of a future quantum computer. An electron not only has a charge but, because of its spin, also behaves as a tiny magnet. In a magnetic field, the spin can point in the same direction as the field or in the opposite direction, but the laws of quantum mechanics also allow the spin to exist in both states simultaneously.
As a result, the spin of an electron is a very promising building block for the yet-to-be-developed quantum computer; a computer that, for certain applications, is far more powerful than a conventional computer.
At first glance it is surprising that the spin can be rotated by an electric field. However, we know from the Theory of Relativity that a moving electron can 'feel' an electric field as though it were a magnetic field. Researchers Katja Nowack and Dr. Frank Koppens therefore forced an electron to move through a rapidly-changing electric field. Working in collaboration with Prof. Yuli V. Nazarov, theoretical researcher at the Kavli Institute of Nanoscience Delft, they showed that it was indeed possible to turn the spin of the electron by doing so.
The advantage of controlling spin with electric fields rather than magnetic fields is that the former are easy to generate. It will also be easier to control various spins independently from one another - a requirement for building a quantum computer - using electric fields. The team, led by Dr. Lieven Vandersypen, is now going to apply this technique to a number of electrons.
The scientists published their work in Science Express on 1 November, 2007.
Adapted from materials provided by Delft University of Technology.

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venerdì 2 novembre 2007

Revolutionary Laser Technique Destroys Viruses And Bacteria Without Damaging Human Cells


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ScienceDaily (Nov. 2, 2007) — Physicists in Arizona State University have designed a revolutionary laser technique which can destroy viruses and bacteria such as AIDS without damaging human cells and may also help reduce the spread of hospital infections such as MRSA.
The research, published on Thursday November 1 in the Institute of Physics' Journal of Physics: Condensed Matter, discusses how pulses from an infrared laser can be fine-tuned to discriminate between problem microorganisms and human cells.
Current laser treatments such as UV are indiscriminate and can cause ageing of the skin, damage to the DNA or, at worst, skin cancer, and are far from 100 per cent effective.
Femtosecond laser pulses, through a process called Impulsive Stimulated Raman Scattering (ISRS), produces lethal vibrations in the protein coat of microorganisms, thereby destroying them. The effect of the vibrations is similar to that of high-pitched noise shattering glass.
The physicists in Arizona have undertaken experiments to show that the coherent vibrations excited by infrared lasers with carefully selected wavelengths and pulse widths do no damage to human cells, most likely because of the different structural compositions in the protein coats of human cells vis a vis bacteria and viruses.
Professor K. T. Tsen from Arizona State University said, "Although it is not clear at the moment why there is a large difference in laser intensity for inactivation between human cells and microorganisms such as bacteria and viruses, the research so far suggests that ISRS will be ready for use in disinfection and could provide treatments against some of the worst, often drug-resistant, bacterial and viral pathogens."
Femtosecond lasers could find immediate application in hospitals as a way to disinfect blood supply or biomaterials and for the treatment of blood-borne diseases such as AIDS and Hepatitis.
Adapted from materials provided by Institute of Physics.

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giovedì 1 novembre 2007

Scientists Discover New Way To Make Water


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ScienceDaily (Nov. 1, 2007) — In a familiar high-school chemistry demonstration, an instructor first uses electricity to split liquid water into its constituent gases, hydrogen and oxygen. Then, by combining the two gases and igniting them with a spark, the instructor changes the gases back into water with a loud pop.
Scientists at the University of Illinois have discovered a new way to make water, and without the pop. Not only can they make water from unlikely starting materials, such as alcohols, their work could also lead to better catalysts and less expensive fuel cells.
"We found that unconventional metal hydrides can be used for a chemical process called oxygen reduction, which is an essential part of the process of making water," said Zachariah Heiden, a doctoral student and lead author of a paper accepted for publication in the Journal of the American Chemical Society, and posted on its Web site.
A water molecule (formally known as dihydrogen monoxide) is composed of two hydrogen atoms and one oxygen atom. But you can't simply take two hydrogen atoms and stick them onto an oxygen atom. The actual reaction to make water is a bit more complicated: 2H2 + O2 = 2H2O + Energy.
In English, the equation says: To produce two molecules of water (H2O), two molecules of diatomic hydrogen (H2) must be combined with one molecule of diatomic oxygen (O2). Energy will be released in the process.
"This reaction (2H2 + O2 = 2H2O + Energy) has been known for two centuries, but until now no one has made it work in a homogeneous solution," said Thomas Rauchfuss, a U. of I. professor of chemistry and the paper's corresponding author.
The well-known reaction also describes what happens inside a hydrogen fuel cell.
In a typical fuel cell, the diatomic hydrogen gas enters one side of the cell, diatomic oxygen gas enters the other side. The hydrogen molecules lose their electrons and become positively charged through a process called oxidation, while the oxygen molecules gain four electrons and become negatively charged through a process called reduction. The negatively charged oxygen ions combine with positively charged hydrogen ions to form water and release electrical energy.
The "difficult side" of the fuel cell is the oxygen reduction reaction, not the hydrogen oxidation reaction, Rauchfuss said. "We found, however, that new catalysts for oxygen reduction could also lead to new chemical means for hydrogen oxidation."
Rauchfuss and Heiden recently investigated a relatively new generation of transfer hydrogenation catalysts for use as unconventional metal hydrides for oxygen reduction.
In their JACS paper, the researchers focus exclusively on the oxidative reactivity of iridium-based transfer hydogenation catalysts in a homogenous, non-aqueous solution. They found the iridium complex effects both the oxidation of alcohols, and the reduction of the oxygen.
"Most compounds react with either hydrogen or oxygen, but this catalyst reacts with both," Heiden said. "It reacts with hydrogen to form a hydride, and then reacts with oxygen to make water; and it does this in a homogeneous, non-aqueous solvent."
The new catalysts could lead to eventual development of more efficient hydrogen fuel cells, substantially lowering their cost, Heiden said.
The work was funded by the U.S. Department of Energy.
Adapted from materials provided by University of Illinois at Urbana-Champaign.

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Nano-assembly Mimics Origin Of Life? Molecules Organize Themselves Into Patterns


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ScienceDaily (Nov. 1, 2007) — The automatic molecular assembly and selection steps exhibited by the molecules, which start as random mixtures, demonstrates a fundamental step in the evolution of life. The organization is activated by instructions which are built-in to the molecules. During assembly, molecules exhibit active selection: those in incorrect positions move to make room for others which fit properly.
The molecular-level observation of such self-selection gives, for the first time, direct insight into fundamental steps of the biological evolution from inanimate molecules to living entities. The resulting nanostructures also hold great promise as an efficient avenue to new catalysts, nanotechnologies, and surface applications.
In the Proceedings of the National Academy of Sciences of the USA, the scientists from the research groups of Klaus Kern at the Max Planck Institute for Solid State Research in Stuttgart (MPI) and of Mario Ruben at the Karlsruhe Institute of Technology (KIT) explain that this observation of molecular organization at surfaces may lead to further insight of how simple, inanimate molecules can build up biological entities of increasing structural and functional complexity, such as membranes, cells, leaves, trees, etc.
"The ability of molecules to selectively sort themselves in highly organized structures is a fundamental requirement for all molecular based systems, including biological organisms," explains Prof. Dr. Klaus Kern, director of the Nanoscale Science Department at the MPI.
Dr. Mario Ruben’s research team at KIT is responsible for designing molecules with built-in instructions, which when read out activate the self-selection process. He comments: "Spontaneous ordering from random mixtures only occurs when built-in instructions are carefully designed and sufficiently strong to initiate successful self-selection."
Scientists at the MPI directly observe the basic step of self-selection by imaging grid-like assemblies of molecules, which have sorted themselves by size. The features of the grid pattern are about one nanometer in size (0.000 000 001 meters), so small that they can only be imaged using state-of-the-art, ultra sensitive microscopy techniques. "Creating such miniscule architectures with features 50 000 times smaller than a hair is not a simple task," according to Dr. Steven Tait of the MPI. "Carving these nanometer structures with current technology would be inefficient and extremely expensive. Our strategy is to utilize instructed building blocks which can arrange themselves into desired structures."
The molecules are placed on ultra-clean metal surfaces and heated gently to enable motion, sorting, and organization. "The molecule movement on the copper surface is restricted to two-dimensions, but is still efficient enough to allow mixing of the molecules. By placing the molecules on a surface, we have the enormous advantage of being able to use specialized microscopes to ‚see’ the nanometer scale structures of the molecular assemblies," explains Alexander Langner, a graduate student at the MPI and first author of the study.
The study was conducted by Alexander Langner, Dr. Steven Tait, Dr. Nian Lin, and Prof. Dr. Klaus Kern of the Max Planck Institute for Solid State Research and Dr. Chandrasekar Rajadurai and Dr. Mario Ruben of the Karlsruhe Institute of Technology (KIT).
Professor Kern is the director of the Nanoscale Science Department at the MPI and leads a large research team conducting a wide range of studies related to the electronic, optical, and chemical properties of novel materials at the nanometer scale. Dr. Ruben is the leader of the research group "Functional Molecular Nanostructures" at the Institute of Nanotechnology in Karlsruhe and has a long-standing competence in the design and synthesis of instructed molecular components.
Adapted from materials provided by Max-Planck-Gesellschaft.

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