'Look Mom No Electricity': Transmitting Information with Chemistry

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Burning an infofuse transmits a sequence of pulses of light, in which information is encoded using different wavelengths (determined by various metallic salts) and the order of the pattern. Image credit: Samuel W. Thomas III, et al. ©2009 PNAS.

(PhysOrg.com) -- While information technology is generally thought to require electrons or photons for transmitting information, scientists have recently demonstrated a third method of transmission: chemical reactions. Based on a flammable “infofuse,” the new system combines information technology and chemistry into a new area the researchers call "infochemistry."

In the study, led by George Whitesides of Harvard University, with other coauthors from Harvard, Tufts University, and DARPA, the scientists explain that their system transmits information in the form of coded pulses of light generated entirely by chemical reactions, without electricity. The system is self-powered, with power being generated by combustion. The power density of the system is higher than that of electrochemical batteries, and has the advantage of not discharging over time.
As Whitesides explained to PhysOrg.com, the significance of the study is that it “demonstrates direct chemical to binary encoding, and transmission of information at a useful bit rate, without batteries.” The researchers hope that their prototype will one day make it possible to make systems that transmit useful information in circumstances in which electronics and batteries do not work, such as harsh environments and under water.
As the scientists explain, the system consists of a strip or fuse of combustible material (nitrocellulose) about 1 mm long. When ignited, a yellow-orange flame moves along the infofuse. To encode information, the scientists patterned the fuse with various metallic salts, which could be done using a desktop inkjet printer or a micropipettor. With their different emission wavelengths, the salts created distinct emission lines in different regions of the electromagnetic spectrum, similar to how the colors of fireworks are made: blue (copper), green (barium), yellow (sodium), red (lithium, strontium, calcium), or near-infrared (potassium, rubidium, cesium).
The infofuse, which burns at about 3-4 cm/sec depending on thickness and pattern spacing, is then read by a detector, such as a color CCD camera or fiber optic cable coupled to a spectrometer. The distance between the detector and burning infofuse was typically 2 m, but the detector could still detect a signal up to 30 m away in daylight.

By coding letters of the alphabet using patterns of metallic salts, the scientists transmitted the phrase, “LOOK MOM NO ELECTRICITY” on a single infofuse using the new technique. As the scientists explain, light pulses have several controllable variables that can be used to represent different letters and symbols. In addition to emission wavelength, other variables include pulse duration, time between pulses, and emission intensity. Using combinations of three alkali metals, the researchers demonstrated how to encode 40 different characters by varying some of these parameters.
“It needs a flame, but it does not need additional batteries or power, or auxiliary devices, to convert a chemical signal to a digital one,” Whitesides said. “The power needed to generate the light is produced by chemistry directly, not by drawing power from a battery.”
Although the current infofuses convert energy into light with only 1% of the efficiency of a battery-operated LED, the infofuses generate 10 times more energy per weight than an alkaline battery generates. In general, integrating information technology and chemistry could have certain advantages, possibly leading to systems that operate beyond binary schemes by using a variety of parameters that allow each information unit to carry more information than a bit. Also, since infochemistry is not bound by the principles of electronics (such as fixed circuitry), but rather the principles of chemistry, new systems could lead to novel architectures.
The scientists hope that further improvements to their system could lead to lightweight, portable, self-powered systems that can transmit information and integrate with modern information technologies. Applications could include environmental sensing and transmitting the data optically over a distance. The system could also be used for message transmission in search-and-rescue type applications.
More information: “Infochemistry and infofuses for the chemical storage and transmission of coded information.” Samuel W. Thomas III, et al. Proceedings of the National Academy of Sciences. vol. 106, no. 23, 9147-9150.

Scientist Finds Plumber's Wonderland On Graphene

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ScienceDaily (June 18, 2009) — Engineers from the University of Pennsylvania, Sandia National Laboratories and Rice University have demonstrated the formation of interconnected carbon nanostructures on graphene substrate in a simple assembly process that involves heating few-layer graphene sheets to sublimation using electric current that may eventually lead to a new paradigm for building integrated carbon-based devices.

Curvy nanostructures such as carbon nanotubes and fullerenes have extraordinary properties but are extremely challenging to pick up, handle and assemble into devices after synthesis. Penn materials scientist Ju Li and Sandia scientist Jianyu Huang have come up with a novel idea to construct curvy nanostructures directly integrated on graphene, taking advantage of the fact that graphene, an atomically thin two-dimensional sheet, bends easily after open edges have been cut on it, which can then fuse with other open edges permanently, like a plumber connecting metal fittings.
The "knife" and "welding torch" used in the experiments, which were performed inside an electron microscope, was electrical current from a Nanofactory scanning probe, generating up to 2000°C of heat. Upon applying the electrical current to few-layer graphene, they observed the in situ creation of many interconnected, curved carbon nanostructures, such as "fractional nanotube"-like graphene bi-layer edges, or BLEs; BLE rings on graphene equivalent to "anti quantum-dots"; and nanotube-BLE assembly connecting multiple layers of graphene.
Remarkably, researchers observed that more than 99 percent of the graphene edges formed during sublimation were curved BLEs rather than flat monolayer edges, indicating that BLEs are the stable edges in graphene, in agreement with predictions based on symmetry considerations and energetic calculations. Theory also predicts these BLEs, or "fractional nanotubes," possess novel properties of their own and may find applications in devices.
Li and Huang observed the creation of these interconnected carbon nanostructures using the heat of electric current and a high-resolution transmission electron microscope. The current, once passed through the graphene layers, improved the crystalline quality and surface cleanness of the graphene as well, both important for device fabrication.
The sublimation of few-layer graphene, such as a 10-layer stack, is advantageous over the sublimation of monolayers. In few-layer graphene, layers spontaneously fuse together forming nanostructures on top of one or two electrically conductive, extended, graphene sheets.
During heating, both the flat graphene sheets and the self-wrapping nanostructures that form, like bilayer edges and nanotubes, have unique electronic properties important for device applications. The biggest obstacle for engineers has been wrestling control of the structure and assembly of these nanostructures to best exploit the properties of carbon. The discoveries of self-assembled novel carbon nanostructures may circumvent the hurdle and lead to new approach of graphene-based electronic devices.
Researchers induced the sublimation of multilayer graphene by Joule-heating, making it thermodynamically favorable for the carbon atoms at the edge of the material to escape into the gas phase, leaving freshly exposed edges on the solid graphene. The remaining graphene edges curl and often welded together to form BLEs. Researchers attribute this behavior to nature's driving force to reduce capillary energy, dangling bonds on the open edges of monolayer graphene, at the cost of increased bending energy.
"This study demonstrates it is possible to make and integrate curved nanostructures directly on flat graphene, which is extended and electrically conducting," said Li, associate professor in the Department of Materials Science and Engineering in Penn's School of Engineering and Applied Science. "Furthermore, it demonstrates that multiple graphene sheets can be intentionally interconnected. And the quality of the plumbing is exceptionally high, better than anything people have used for electrical contacts with carbon nanotubes so far. We are currently investigating the fundamental properties of graphene bi-layer edges, BLE rings and nanotube-BLE junctions."
Short movies of the fabrication of these nanostructures can be viewed at http://www.youtube.com/user/MaterialsTheory.
The study is published in the current issue of the journal Proceedings of the National Academy of Sciences. The study was performed by Li and Liang Qi of Penn, Jian Yu Huang and Ping Lu of the Center for Integrated Nanotechnologies at Sandia and Feng Ding and Boris I. Yakobson of the Department of Mechanical Engineering and Materials Science at Rice.
It was supported by the National Science Foundation, the Air Force Office of Scientific Research, the Honda Research Institute, the Department of Energy and the Office of Naval Research.
Adapted from materials provided by University of Pennsylvania.

Most Efficient And Stable Source Of Pure White Light Ever Achieved

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ScienceDaily (June 19, 2009) — Researchers are reporting the first use of a fundamentally new approach in the quest to snare the Holy Grail of the lighting industry: An LED (light-emitting diode) — those ultra-efficient, long-lived light sources — that emits pure white light. The new approach yielded what the scientists describe as the most efficient and stable source of pure white light ever achieved. The advance could speed the development of this next-generation technology for improved lighting of homes, offices, displays, and other applications, they say.

Soo Young Park and colleagues note that white LEDs show promise as a brighter, longer-lasting and more energy-efficient light source than conventional lighting, such as incandescent and fluorescent lights, which they may replace in the future. But scientists have had difficulty producing white LEDs that are suitable for practical use. Existing technologies produce tinted shades of white light, require complex components, and become unstable over time.
The researchers describe development of a new, simpler white LED that is the first to achieve stable white light emissions using a single molecule. Their specially engineered molecule combines two light-emitting materials, one orange and one blue, which together produce white light over the entire visible range. In laboratory studies, the scientists showed that light production from an LED using the new molecule was highly efficient and had excellent color stability and reproducibility, features that make it a practical white light source.
Journal reference:
Park et al. A White-Light-Emitting Molecule: Frustrated Energy Transfer between Constituent Emitting Centers. Journal of the American Chemical Society, 2009; 090610145759060 DOI: 10.1021/ja902533f
Adapted from materials provided by American Chemical Society.

ATLAS (LHC,CERN) e-News: It’s like déjà-vu all over again

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In the movie Groundhog Day, a reporter is forced to re-live a day (February 2) over and over again. Perhaps the coming LHC re-startup would feel like Groundhog Day to some science reporters. CERN therefore has no plans to invite the media here for the first beams this autumn. The first collisions at 450 on 450 GeV (hopefully a short time later) will also be kept low key. What is not fully decided is how to handle the first high-energy collisions and the first events from ATLAS and the other experiments.The images from last September (both control room scenes and the splash events) made a vivid impression on the news media and the public. This time ATLAS will not allow reporters within the Control Room, but the new Visitor Center allows a view of the activities, and new high-quality cameras (mounted on the back wall) can provide the video footage the media wants. The ATLAS website had more than two million hits during the September 2008 activities.Rumors are swirling that Tom Hanks may return to CERN to “turn on” the LHC, but of course that depends on the schedules of Hanks and the LHC. There are several stages in the startup process that could be defined as “turn-on”.Four members of the ATLAS outreach group have been travelling to Sony Pictures (near Hollywood) to help develop a 15-minute CERN/ATLAS “extra” that will be added to the DVD of Angels & Demons that will be released in November. We have also requested to get a copy of the five-minute segment near the beginning of the movie that has some spectacular cinematography of ATLAS. Have you seen our ATLAS webpages on antimatter at http://atlas.ch/angels-demons/ and the new exhibition in the Globe? Finally there have been at least 60 very successful lectures worldwide discussing the science of the movie and the science of LHC.In other news, design work is in progress to replace the aging posters in the Bldg. 40 café. The idea is to make the café an appealing place for physicists to chat and sip coffee, as well as to make it an interesting place to bring visitors to show them the basics of ATLAS.If you haven’t seen modern pop-up books, you will be surprised by the complexity they can portray. ATLAS will soon have its own dramatic pop-up book, a production led by Emma Sanders. It portrays both the detector and the physics.Work is in progress on an animation in the style of the ATLAS animations Episodes I and II. This new project is a joint effort with CMS to portray the physics of the LHC. Two professional animators are working on the project, and a senior person at Pixar has been consulting periodically. Completion date is approximately October 2009. Thought is also being given to an update of the 12-year-old ATLAS movie. All of our videos are on YouTube. Both CERN and ATLAS are working on new/updated communication plans. In the case of CERN, a draft plan has been circulated amongst the experiments. The ATLAS plan is in progress and should be completed in June.These are just the highlights of our activities. You can catch up on the whole series of outreach efforts at the next ATLAS overview week.

Michael Barnett
ATLAS Outreach

Manipulating light on a chip for quantum technologies

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An artist's impression of the on-chip quantum metrology experiment (making ultraprecise measurements on chip) Photo by Will Amery, University of Bristol.

(PhysOrg.com) -- A team of physicists and engineers at Bristol University has demonstrated exquisite control of single particles of light — photons — on a silicon chip to make a major advance towards long-sought-after quantum technologies, including super-powerful quantum computers and ultra-precise measurements.

The Bristol Centre for Quantum Photonics has demonstrated precise control of four photons using a microscopic metal electrode lithographically patterned onto a silicon chip.
The photons propagate in silica waveguides — much like in optical fibres — patterned on a silicon chip, and are manipulated with the electrode, resulting in a high-performance miniaturized device.
“We have been able to generate and manipulate entangled states of photons on a silicon chip” said PhD student, Jonathan Matthews, who together with Alberto Politi performed the experiments. “These entangled states are responsible for famously ‘weird’ behaviour arising in quantum mechanics, but are also at the heart of powerful quantum technologies.”
“This precise manipulation is a very exciting development for fundamental science as well as for future quantum technologies.” said Prof Jeremy O’Brien, Director of the Centre for Quantum Photonics, who led the research.
The team reports its results in the latest issue of Nature Photonics [June 2009], a sister journal of the leading science journal Nature, and in a Postdeadline Paper at 'The International Quantum Electronics Conference (IQEC)' on June 4 in Baltimore, USA [IQEC Postdeadline Papers].
Quantum technologies with photons
Quantum technologies aim to exploit the unique properties of quantum mechanics, the physics theory that explains how the world works at microscopic scales.
For example a quantum computer relies on the fact that quantum particles, such as photons, can exist in a “superposition” of two states at the same time — in stark contrast to the transistors in a PC which can only be in the state “0” or “1”.
Photons are an excellent choice for quantum technologies because they are relatively noise-free; information can be moved around at the speed of light; and manipulating single photons is easy.
Making two photons “talk” to each other to generate the all-important entangled states is much harder, but Professor O’Brien and his colleagues at the University of Queensland demonstrated this in a quantum logic gate back in 2003 [Nature 426, 264 (2003)].

Last year, the Centre for Quantum Photonics at Bristol showed how such interactions between photons could be realised on a silicon chip, pointing the way to advanced quantum technologies based on photons [Science 320, 646 (2008)].
Photons are also required to “talk” to each other to realise the ultra-precise measurements that harness the laws of quantum mechanics. In 2007 Professor O’Brien and his Japanese collaborators reported such a quantum metrology measurement with four photons [Science 316, 726 (2007)].
Manipulating photons on a silicon chip
“Despite these impressive advances, the ability to manipulate photons on a chip has been missing,” said Mr Politi. “For the last several years the Centre for Quantum Photonics has been working towards building fully functional quantum circuits on a chip to solve these problems,” added Prof O’Brien.
The team coupled photons into and out of the chip, fabricated at CIP Technologies, using optical fibres. Application of a voltage across the metal electrode changed the temperature of the silica waveguide directly beneath it, thereby changing the path that the photons travelled. By measuring the output of the device they confirmed high-performance manipulation of photons in the chip.
The researchers proved that one of the strangest phenomena of the quantum world, namely “quantum entanglement”, was achieved on-chip with up to four photons. Quantum entanglement of two particles means that the state of either of the particles is not defined, but only their collective state, and results in an instantaneous linking of the particles.
This on-chip entanglement has important applications in quantum metrology and the team demonstrated an ultra-precise measurement in this way.
“As well as quantum computing and quantum metrology, on-chip photonic quantum circuits could have important applications in quantum communication, since they can be easily integrated with optical fibres to send photons between remote locations,” said Alberto Politi.
“The really exciting thing about this result is that it will enable the development of reconfigurable and adaptive quantum circuits for photons. This opens up all kinds of possibilities,” said Prof O’Brien.
A commentary on the work that appeared in the same issue [Nature Photonics 3, 317 (2009)] described it as “an important step in the quest for quantum computation” and concluded: “The most exciting thing about this work is its potential for scalability. The small size of the [device] means that far greater complexity is possible than with large-scale optics.”
The other co-author of the Nature Photonics paper is Dr André Stefanov, formerly a Research fellow in the Centre for Quantum Photonics, and now at the Federal Office of Metrology METAS, Switzerland.
Provided by University of Bristol (news : web)

'Colossal' Magnetic Effect Under Pressure

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The structure models for F-type and A-type magnetic ordering in manganite in response to pressure. The arrows inside orbitals indicate the spin direction of d electrons.

(PhysOrg.com) -- Millions of people today carry around pocket-sized music players capable of holding thousands of songs, thanks to the discovery 20 years ago of a phenomenon known as the “giant magnetoresistance effect,” which made it possible to pack more data onto smaller and smaller hard drives. Now scientists are on the trail of another phenomenon, called the “colossal magnetoresistance effect” (CMR) which is up to a thousand times more powerful and could trigger another revolution in computing technology.

Understanding, and ultimately controlling, this effect and the intricate coupling between electrical conductivity and magnetism in these materials remains a challenge, however, because of competing interactions in manganites, the materials in which CMR was discovered. In the June 12, 2009, issue of the journal Physical Review Letters, a team of researchers report new progress in using high pressure techniques to unravel the subtleties of this coupling.
To study the magnetic properties of manganites, a form of manganese oxide, the research team, led by Yang Ding of the Carnegie Institution’s High Pressure Synergetic Center (HPSync), applied techniques called x-ray magnetic circular dichroism (XMCD) and angular-dispersive diffraction at the Advanced Photon Source (APS) of Argonne National Laboratory in Illinois. High pressure XMCD is a newly developed technique that uses high-brilliance circularly polarized x-rays to probe the magnetic state of a material under pressures of many hundreds of thousands of atmospheres inside a diamond anvil cell.
The discovery of CMR in manganite compounds has already made manganites invaluable components in technological applications. An example is magnetic tunneling junctions in soon-to-be marketed magnetic random access memory (MRAM), where the tunneling of electrical current between two thin layers of manganite material separated by an electrical insulator depends on the relative orientation of magnetization in the manganite layers. Unlike conventional RAM, MRAM could yield instant-on computers. However, no current theories can fully explain the rich physics, including CMR effects, seen in manganites.
“The challenge is that there are competing interactions in manganites among the electrons that determine magnetic properties,” said Ding. “And the properties are also affected by external stimuli, such as, temperature, pressure, magnetic field, and chemical doping.”
“Pressure has a unique ability to tune the electron interactions in a clean and theoretically transparent manner,” he added. “It is a direct and effective means for manipulating the behavior of electrons and could provide valuable information on the magnetic and electronic properties of manganite systems. But of all the effects, pressure effects have been the least explored.”

The researchers found that when a manganite was subjected to conditions above 230,000 times atmospheric pressure it underwent a transition in which its magnetic ordering changed from a ferromagnetic type (electron spins aligned) to an antiferromagnetic type (electron spins opposed). This transition was accompanied by a non-uniform structural distortion called the Jahn-Teller effect.
“It is quite interesting to observe that uniform compression leads to a non-uniform structural change in a manganite, which was not predicted by theory,” said Ding, “Working with Michel van Veenendaal’s theoretical group at APS, we found that the predominant effect of pressure on this material is to increase the strength of an interaction known as superexchange relative to another known as the double exchange interaction. A consequence of this is that the overall ferromagnetic interactions in the system occur in a plane (two dimensions) rather than in three dimensions, which produces a non-uniform redistribution of electrons. This leads to the structural distortion.”
Another intriguing response of manganite to high pressure revealed by the experiments is that the magnetic transition did not occur throughout the sample at the same time. Instead, it spread incrementally.
“The results imply that even at ambient conditions, the manganite might already have two separate magnetic phases at the nanometer scale, with pressure favoring the growth of the antiferro-magnetic phase at the expense of the ferromagnetic phase,” said coauthor Daniel Haskel, a physicist at Argonne’s APS. “Manipulating phase separation at the nanoscale level is at the very core of nanotechnology and manganites provide an excellent playground to pursue this objective”.
“This work not only displays another interesting emergent phenomenon arising from the interplay between charge, spin, orbital and lattice in a strongly correlated electron system,” commented coauthor Dr. Ho-kwang Mao of Carnegie’s Geophysical Laboratory, Director of HPSync,” but it also manifests the role of pressure in magnetism studies of dense matter.”
More information: Pressure-induced magnetic transition in manganite (La0.75Ca0.25MnO3) Yang Ding, Daniel Haskel, Yuan-Chieh Tseng, Eiji Kaneshita, Michel van Veenendaal, John Mitchell, Stanislav V. Sinogeikin, Vitali Prakapenka, and Ho-kwang Mao, Physical Review Letters, June 2009.

Provided by Carnegie Institution

Lasers Are Making Solar Cells Competitive

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ScienceDaily (June 4, 2009) — Solar electricity has a bright future: It is renewable and available in unlimited quantities, and it does not produce any gases detrimental to the climate. Its only drawback right now is the price: the electric power currently being produced by solar cells in northern Europe must be subsidized if it is to compete against the household electricity generated by traditional power plants. At "Laser 2009" in Munich, June 15 to 18, Fraunhofer researchers will be demonstrating how laser technology can contribute to optimizing the manufacturing costs and efficiency of solar cells.

Cell phones, computers, MP3 players, kitchen stoves, and irons all have one thing in common: They need electricity. And in the future, more and more cars will also be fuelled by electric power. If the latest forecast from the World Energy Council WEC can be believed, global electricity requirements will double in the next 40 years. At the same time, prices for the dwindling resources of petroleum and natural gas are climbing.
“Rising energy prices are making alternative energy sources increasingly cost-effective. Sometime in the coming years, renewable energy sources, such as solar energy, will be competitive, even without subsidization,” explains Dr. Arnold Gillner, head of the microtechnology department at the Fraunhofer Institute for Laser Technology in Aachen, Germany. “Experts predict that grid parity will be achieved in a few years. This means that the costs and opportunities in the grid will be equal for solar electricity and conventionally generated household electricity.” Together with his team at the Fraunhofer Institute for Laser Technology ILT in Aachen, this researcher is developing technologies now that will allow faster, better, and cheaper production of solar cells in the future. “Lasers work quickly, precisely, and without contact. In other words, they are an ideal tool for manufacturing fragile solar cells. In fact, lasers are already being used in production today, but there is still considerable room for process optimization.” In addition to gradually improving the manufacturing technology, the physicists and engineers in Aachen are working with solar cell developers - for example, at the Fraunhofer Institute for Solar Energy Systems ISE in Freiburg - on new engineering and design alternatives.
New production technologies allow new design alternatives
At “Laser 2009” in Munich, the researchers will be demonstrating how lasers can drill holes into silicon cells at breathtaking speed: The ILT laser system drills more than 3,000 holes within one second. Because it is not possible to move the laser source at this speed, the experts have developed optimized manufacturing systems which guide and focuses the light beam at the required points. “We are currently experimenting with various laser sources and optical systems,” Gillner explains. “Our goal is to increase the performance to 10,000 holes a second. This is the speed that must be reached in order to drill 10,000 to 20,000 holes into a wafer within the cycle time of the production machines.”
The tiny holes in the wafer - their diameter is only 50 micrometers – open up undreamt-of possibilities for the solar cell developers. “Previously, the electrical contacts were arranged on the top of the cells. The holes make it possible to move the contacts to the back, with the advantage that the electrodes, which currently act as a dark grid to absorb light, disappear. And so the energy yield increases. The goal is a degree of efficiency of 20 percent% in industrially-produced emitter wrap-through (EWT) cells, with a yield of one-third more than classic silicon cells,” Gillner explains. The design principle itself remains unchanged: In the semi-conductor layer, light particles, or photons, produce negative electrons and positive holes, each of which then wanders to the oppositely poled electrodes. The contacts for anodes and cathodes in the EWT cells are all on the back, there is no shading caused by the electrodes, and the degree of efficiency increases. With this technique, it may one day be possible to use unpurified “dirty” silicon to manufacture solar cells that have poorer electrical properties, but that are cheaper.
Drilling holes into silicon cells is only one of many laser applications in solar cell manufacturing. In the EU project Solasys – Next Generation Solar Cell and Module Laser Processing Systems – an international research team is currently developing new technologies that will allow production to be optimized in the future. ILT in Aachen is coordinating the six million euro project. “We are working on new methods that make the doping of semiconductors, the drilling and the surface structuring of silicon, the edge isolation of the cells, and the soldering of the modules more economical,” project coordinator Gillner explains. For example, “selective laser soldering” makes it possible to improve the rejection rates and quality of the contacting, and so reduce manufacturing costs. Until now, the electrodes were mechanically pressed onto the cells, and then heated in an oven. “But silicon cells often break during this process,” Gillner knows. “Breakage is a primary cost factor in production.” On the other hand, however, with “selective laser soldering” the contacts are pressed on to the cells with compressed air and then soldered with the laser. The mechanical stress approaches zero and the temperature can be precisely regulated. The result: Optimal contacts and almost no rejects.
Laser technology means more efficient thin film cells
Laser technology is also helping to optimize the manufacture of thin film solar cells. The extremely thin film packages made of semiconducting oxide, amorphous silicon, and metal that are deposited onto the glass panels still have a market share of only ten percent. But as Gillner knows, “This could be higher, because thin film solar cells can be used anywhere that non-transparent glass panels can be mounted, for example, on house facades or sound-insulating walls. But the degrees of efficiency are comparable low at five to eight percent, and the production costs are comparatively high.” The laser researchers are working to improve these costs. Until now, the manufacturers have used mechanical methods or solid-state lasers in the nanosecond range in order to structure the active layers on the glass panels. In order to produce electric connections between the semiconductor and the metal, grooves only a few micrometers wide must be created. At the Fraunhofer-Gesellschaft booth at “Laser 2009” the ILT researchers will be demonstrating a 400-watt ultrashort pulse laser that processes thin-film solar modules ten times faster than conventional diode-pumped solid-state lasers. “The ultrashort pulse laser is an ideal tool for ablating thin layers: It works very precisely, does not heat the material and, working with a pulse frequency of 80 MHz, can process a 2-by-3 meter glass panel in under two minutes,” Gillner reports. “The technology is still very new, and high-performance scanning systems and optical systems adapted to the process must be developed first. In the medium term, however, this technology will be able to reduce production costs.”
The rise of laser technology in solar technology is just taking off, and it still has a long way to go. “Lasers simplify and optimize the manufacture of classic silicon and thin-film cells, and they allow the development of new design alternatives,” Gillner continues. “And so laser technology is making an important contribution towards allowing renewable energy sources to penetrate further into the energy market.”
Adapted from materials provided by Fraunhofer-Gesellschaft.

Theorists Reveal Path To True Muonium -- Never-seen Atom

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ScienceDaily (June 4, 2009) — True muonium, a long-theorized but never-seen atom, might be observed in future experiments, thanks to recent theoretical work by researchers at the Department of Energy's SLAC National Accelerator Laboratory and Arizona State University. True muonium was first theorized more than 50 years ago, but until now no one had uncovered an unambiguous method by which it could be created and observed.

"We don't usually work in this area, but one day we were idly talking about how experimentalists could create exotic states of matter," said SLAC theorist Stanley Brodsky, who worked with Arizona State's Richard Lebed on the result. "As our conversation progressed, we realized 'Gee…we just figured out how to make true muonium.'"
True muonium is made of a muon and an anti-muon, and is distinguished from what's also been called "muonium"—an atom made of an electron and an anti-muon. Both muons and anti-muons are created frequently in nature when energetic particles from space strike the earth's atmosphere. Yet both have a fleeting existence, and their combination, true muonium, decays naturally into other particles in a few trillionths of a second. This makes observation of the exotic atom quite difficult.
In a paper published this week in Physical Review Letters, Brodsky and Lebed describe two methods by which electron–positron accelerators could detect the signature of true muonium's formation and decay.
In the first method, an accelerator's electron and positron beams are arranged to merge, crossing at a glancing angle. Such a collision would produce a single photon, which would then transform into a single true muonium atom that would be thrown clear of the other particle debris. Because the newly created true muonium atoms would be traveling so fast that the laws of relativity govern, they would decay much slower than they would otherwise, making detection easier. [An artist's impression of this process can be seen at right.]
In the second method, the electron and positron beams collide head-on. This would produce a true muonium atom and a photon, tangled up in a cloud of particle debris. Yet simply by recoiling against each other, the true muonium and the photon would push one another out of the debris cloud, creating a unique signature not previously searched for.
"It's very likely that people have already created true muonium in this second way," Brodsky said. "They just haven't detected it."
In their paper, Lebed and Brodsky also describe a possible, but more difficult, means by which experimentalists could create true tauonium, a bound state of a tau lepton and its antiparticle. The tau was first created at SLAC's SPEAR storage ring, a feat for which SLAC physicist Martin Perl received the 1995 Nobel Prize in physics.
Brodsky attributes the pair's successful work to a confluence of events: various unrelated lectures, conversations and ideas over the years, pieces of which came together suddenly during his conversation with Lebed.
"Once you pull all of the ideas together, you say 'Of course! Why not?' Brodsky said. "That's the process of science—you try to relate everything new to what you already know, creating logical connections."
Now that those logical connections are firmly in place, Brodsky said he hopes that one of the world's colliders will perform the experiments he and Lebed describe, asking, "Who doesn't want to see a new form of matter that no one's ever seen before?"
Journal reference:
Stanley J. Brodsky and Richard F. Lebed. Production of the Smallest QED Atom: True Muonium (µ µ-). Physical Review Letters, 2009; DOI: 10.1103/PhysRevLett.102.213401
Adapted from materials provided by DOE/SLAC National Accelerator Laboratory.

Scientists Demonstrate All-fiber Quantum Logic

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ScienceDaily (June 4, 2009) — A team of physicists and engineers have demonstrated all-fiber quantum logic, where single photons are generated and used to perform the contolled-NOT quantum logic gate in optical fibers with high fidelity.

The only quantum technology in practical use today is quantum cryptography and is currently limited in the distance over which secure communication may occur.
More sophisticated quantum networks will require multiple nodes with the ability to implement small-scale quantum processing in order to increase the range of quantum communications. Such networks will rely on optical fiber links, making fiber-based photon generation and information processing of key technological importance.
Jeremy O’Brien, Professor of Physics and Electrical Engineering at Bristol University and colleagues, have shown it is possible for a high-fidelity fiber controlled-NOT gate to operate with fiber heralded single-photon sources.
Professor O’Brien speaking about the research, said: “On the basis of a simple model we are able to conclude that imperfections are primarily due to the photon sources, meaning that the gate itself works with very high fidelity.”
“Such all fiber quantum information processing will likely have important applications in future quantum networks.”
All-fiber quantum information processing could be used in less mature quantum technologies such as computing, communication and advanced measurement, as well as in the fundamental science of quantum optics.
The team reported its results in the March 2009 issue of Physical Review A (Vol 79, No 3).
Journal reference:
Alex S. Clark, Jérémie Fulconis, John G. Rarity, William J. Wadsworth, and Jeremy L. O%u2018Brien. All-optical-fiber polarization-based quantum logic gate. Physical Review A, 2009; 79 (3): 030303 DOI: 10.1103/PhysRevA.79.030303
Adapted from materials provided by University of Bristol.

Regular Light Bulbs Made Super-Efficient with Ultra-Fast Laser

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Chunlei Guo stands in front of his femtosecond laser, which can double the efficiency of a regular incandescent light bulb. Credit: University of Rochester
(PhysOrg.com) -- An ultra-powerful laser can turn regular incandescent light bulbs into power-sippers, say optics researchers at the University of Rochester. The process could make a light as bright as a 100-watt bulb consume less electricity than a 60-watt bulb while remaining far cheaper and radiating a more pleasant light than a fluorescent bulb can.

The laser process creates a unique array of nano- and micro-scale structures on the surface of a regular tungsten filament—the tiny wire inside a light bulb—and theses structures make the tungsten become far more effective at radiating light.
The findings will be published in an upcoming issue of the journal Physical Review Letters.
"We've been experimenting with the way ultra-fast lasers change metals, and we wondered what would happen if we trained the laser on a filament," says Chunlei Guo, associate professor of optics at the University of Rochester. "We fired the laser beam right through the glass of the bulb and altered a small area on the filament. When we lit the bulb, we could actually see this one patch was clearly brighter than the rest of the filament, but there was no change in the bulb's energy usage."
The key to creating the super-filament is an ultra-brief, ultra-intense beam of light called a femtosecond laser pulse. The laser burst lasts only a few quadrillionths of a second. To get a grasp of that kind of speed, consider that a femtosecond is to a second what a second is to about 32 million years. During its brief burst, Guo's laser unleashes as much power as the entire grid of North America onto a spot the size of a needle point. That intense blast forces the surface of the metal to form nanostructures and microstructures that dramatically alter how efficiently can radiate from the filament.
In 2006, Guo and his assistant, Anatoliy Vorobeyv, used a similar laser process to turn any metal pitch black. The surface structures created on the metal were incredibly effective at capturing incoming radiation, such as light.
"There is a very interesting 'take more, give more' law in nature governing the amount of light going in and coming out of a material," says Guo. Since the black metal was extremely good at absorbing light, he and Vorobyev set out to study the reverse process—that the blackened filament would radiate light more effectively as well.

"We knew it should work in theory," says Guo, "but we were still surprised when we turned up the power on this bulb and saw just how much brighter the processed spot was."
In addition to increasing the brightness of a bulb, Guo's process can be used to tune the color of the light as well. In 2008, his team used a similar process to change the color of nearly any metal to blue, golden, and gray, in addition to the black he'd already accomplished. Guo and Vorobeyv used that knowledge of how to control the size and shape of the nanostructures—and thus what colors of light those structures absorb and radiate—to change the amount of each wavelength of light the tungsten filament radiates. Though Guo cannot yet make a simple bulb shine pure blue, for instance, he can change the overall radiated spectrum so that the tungsten, which normally radiates a yellowish light, could radiate a more purely white light.
Guo's team has even been able to make a filament radiate partially polarized light, which until now has been impossible to do without special filters that reduce the bulb's efficiency. By creating nanostructures in tight, parallel rows, some light that emits from the filament becomes polarized.
The team is now working to discover what other aspects of a common light bulb they might be able to control. Fortunately, despite the incredible intensity involved, the femtosecond laser can be powered by a simple wall outlet, meaning that when the process is refined, implementing it to augment regular light bulbs should be relatively simple.
Guo is also announcing this month in Applied Physics Letters a technique using a similar femtosecond laser process to make a piece of metal automatically move liquid around its surface, even lifting a liquid up against gravity.
Source: University of Rochester (news : web)

World's largest laser opens: We are close to practice the nuclear fusion

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Scientists for decades have been hunting for ways to harness the enormous force of the sun and stars to supply energy here on Earth. The National Ignition Facility at the Lawrence Livermore Laboratory may spark the light at the end of the tunnel.

The facility was dedicated today (May 29) at a ceremony attended by numerous state and national officials.
Roughly the size of three football fields, the facility houses the world’s largest laser. Within the next three years, its 192 laser beams will deliver massive amounts of energy at a pea-sized target. That target, filled with hydrogen fuel, will in turn release 10 to 100 times the power than the amount injected by the laser.

When all of the lasers’ energy slams the target, it will generate unprecedented temperatures in the target materials - temperatures of more than 100 million degrees and pressures more than 100 billion times the Earth’s atmosphere. These conditions are similar to those in the stars and the cores of giant planets. Igniting these conditions will create nuclear fusion, which is the reaction that gives the sun and the stars their immense power. Mimicking and controlling the highly volatile process - tantamount to creating a star in a laboratory - could lead to ways to produce plentiful clean and safe energy.
While demonstrating nuclear fusion as a viable means for abundant clean energy may be the most exciting offshoot of NIF research, another of its roles is to study the conditions associated with the inner workings of nuclear weapons.
The NIF is a cornerstone of a critical national security mission to ensure the reliability and safety of the U.S. nuclear stockpile without conducting underground testing. At NIF, scientists will be able to provide data for supercomputer simulations that replicate conditions that exist inside a thermonuclear weapon.
NIF experiments will also help scientists who are trying to understand the universe in many fundamental ways, including astrophysicists learning about the hot, dense interiors of large planets, stars and other phenomena.
Provided by University of California

Researchers make breakthrough in the quantum control of light

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This image represents a quantum state with zero, three and six photons simultaneously. The theory is on left and the experiment is on the right. Image: UCSB.
Researchers at UC Santa Barbara have recently demonstrated a breakthrough in the quantum control of photons, the energy quanta of light. This is a significant result in quantum computation, and could eventually have implications in banking, drug design, and other applications.

In a paper to be published in today's issue of the journal Nature, UCSB physics researchers Max Hofheinz, John Martinis, and Andrew Cleland document how they used a superconducting electronic circuit known as a Josephson phase qubit to prepare highly unusual quantum states using microwave-frequency photons. The breakthrough is the result of four years of work in the laboratories of Cleland and Martinis.
The project is funded by the federal agency called the Intelligence Advanced Research Projects Activity, or IARPA. The government is particularly interested in quantum computing because of the way banking and other important communications are currently encrypted. Using large numbers, with hundreds of digits, encryption codes are changed daily and would take years of traditional computing to break. Quantum computing could potentially break those codes quickly, destroying current encryption schemes.
In the experiments, the photons were stored in a microwave cavity, a "light trap" in which the light bounces back and forth as if between two mirrors. In earlier work, these researchers showed they could create and store photons, one at a time, with up to 15 photons stored at one time in the light trap. The research shows that they can create states in which the light trap simultaneously has different numbers of photons stored in it. For example, it can simultaneously have zero, three, and six photons at the same time. Measuring the quantum state by counting how many photons are stored forces the trap to "decide" how many there are; but prior to counting, the light trap exists in a quantum superposition, with all three outcomes possible.
Explaining the paradoxical simultaneity of quantum states, Cleland said that it's like having your cake and eating it -- at the same time.
"These superposition states are a fundamental concept in quantum mechanics, but this is the first time they have been controllably created with light," Cleland said. Martinis added, "This experiment can be thought of as a quantum digital-to-analog converter." As digital-to-analog converters are key components in classical communication devices (for example, producing the sound waveforms in cell phones), this experiment might enable more advanced communication protocols for the transmission of quantum information.
First author Hofheinz designed and performed the measurements. He is a postdoctoral researcher from Germany who has been working at UCSB for the last two years on this project. The devices used to perform the experiment were made by Haohua Wang, a postdoctoral researcher from China, who is second author on the Nature publication.
The scientists said their research is leading to the construction of a quantum computer, which will have applications in information encryption and in solving or simulating problems that are not amenable to solution using standard computers.
Source: University of California - Santa Barbara (news : web)

Theorists Reveal Path to True Muonium

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In this artist's depiction of how experimentalists could create true muonium, an electron (blue) and a positron (red) collide, producing a virtual photon (green) and then a muonium atom, made of a muon (small yellow) and an anti-muon (small purple). The muonium atom then decays back into a virtual photon and then a positron and an electron. Overlaying this process is a figure indicating the structure of the muonium atom: one muon (large yellow) and one anti-muon (large purple). Credit: Graphic: Terry Anderson/SLAC
(PhysOrg.com) -- True muonium, a long-theorized but never-seen atom, might be observed in future experiments, thanks to recent theoretical work by researchers at the Department of Energy's SLAC National Accelerator Laboratory and Arizona State University. True muonium was first theorized more than 50 years ago, but until now no one had uncovered an unambiguous method by which it could be created and observed.

"We don't usually work in this area, but one day we were idly talking about how experimentalists could create exotic states of matter," said SLAC theorist Stanley Brodsky, who worked with Arizona State's Richard Lebed on the result. "As our conversation progressed, we realized 'Gee…we just figured out how to make true muonium.'"
True muonium is made of a muon and an anti-muon, and is distinguished from what's also been called "muonium"—an atom made of an electron and an anti-muon. Both muons and anti-muons are created frequently in nature when energetic particles from space strike the earth's atmosphere. Yet both have a fleeting existence, and their combination, true muonium, decays naturally into other particles in a few trillionths of a second. This makes observation of the exotic atom quite difficult.
In a paper published on Tuesday in Physical Review Letters, Brodsky and Lebed describe two methods by which electron-positron accelerators could detect the signature of true muonium's formation and decay.
In the first method, an accelerator's electron and positron beams are arranged to merge, crossing at a glancing angle. Such a collision would produce a single photon, which would then transform into a single true muonium atom that would be thrown clear of the other particle debris. Because the newly created true muonium atoms would be traveling so fast that the laws of relativity govern, they would decay much slower than they would otherwise, making detection easier.
In the second method, the electron and positron beams collide head-on. This would produce a true muonium atom and a photon, tangled up in a cloud of particle debris. Yet simply by recoiling against each other, the true muonium and the photon would push one another out of the debris cloud, creating a unique signature not previously searched for.
"It's very likely that people have already created true muonium in this second way," Brodsky said. "They just haven't detected it."
In their paper, Lebed and Brodsky also describe a possible, but more difficult, means by which experimentalists could create true tauonium, a bound state of a tau lepton and its antiparticle. The tau was first created at SLAC's SPEAR storage ring, a feat for which SLAC physicist Martin Perl received the 1995 Nobel Prize in physics.
Brodsky attributes the pair's successful work to a confluence of events: various unrelated lectures, conversations and ideas over the years, pieces of which came together suddenly during his conversation with Lebed.
"Once you pull all of the ideas together, you say 'Of course! Why not?' Brodsky said. "That's the process of science—you try to relate everything new to what you already know, creating logical connections."
Now that those logical connections are firmly in place, Brodsky said he hopes that one of the world's colliders will perform the experiments he and Lebed describe, asking, "Who doesn't want to see a new form of matter that no one's ever seen before?"

More information: "Production of the Smallest QED Atom: True Muonium," Physical Review Letters
Source: SLAC National Accelerator Laboratory (news : web)

Super-efficient Transistor Material Predicted

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(PhysOrg.com) -- New work by condensed-matter theorists at the Stanford Institute for Materials and Energy Science at SLAC National Accelerator Laboratory points to a material that could one day be used to make faster, more efficient computer processors.

In a paper published online Sunday in Nature Physics, SIMES researchers Xiao-Liang Qi and Shou-Cheng Zhang, with colleagues from the Chinese Academy of Sciences and Tsinghua University in Beijing, predict that a room temperature material will exhibit the quantum spin Hall effect. In this exotic state of matter, electrons flow without dissipating heat, meaning a transistor made of the material would be drastically more efficient than anything available today. This effect was previously thought to occur only at extremely low temperatures. Now the race is on to confirm the room-temperature prediction experimentally.
Zhang has been one of the leading physicists working on the quantum spin Hall effect; in 2006 he predicted its existence in mercury telluride, which experimentalists confirmed a year later. However, the mercury telluride had to be cooled by liquid helium to a frigid 30 millikelvins, much too cold for real-world applications.
In their hunt for a material that exhibited the quantum spin Hall effect, Zhang and Qi knew they were looking for a solid with a highly unusual energy landscape. In a normal semiconductor, the outermost electrons of an atom prefer to stay in the valence band, where they are orbiting atoms, rather than the higher-energy conduction band, where they move freely through the material. Think of the conduction band as a flat plain pitted with small valence-band valleys. Electrons naturally "roll" down into these valleys and stay there, unless pushed out. But in a material that exhibits the quantum spin Hall effect, this picture inverts; the valence-band valleys rise to become hills, and the electrons roll down to roam the now lower-energy conduction band plain. In mercury telluride, this inversion did occur, but just barely; the hills were so slight that a tiny amount of energy was enough to push the electrons back up, meaning the material had to be kept extremely cold.
When Zhang, Qi and their colleagues calculated this energy landscape for four promising materials, three showed the hoped-for inversion. In one, bismuth selenide, the theoretical conduction band plain is so much lower than the valence band hills that even room temperature energy can't push the electrons back up. In physics terms, the conduction band and valence band are now inverted, with a sizeable difference between them.

"The difference [from mercury telluride] is that the gap is much larger, so we believe the effect could happen at room temperature," Zhang explained.
Materials that exhibit the quantum spin Hall effect are called topological insulators; a chunk of this material acts like an empty metal box that's completely insulating on the inside, but conducting on the surface. Additionally, the direction of each electron's movement on the surface decides its spin, an intrinsic property of electrons. This leads to surprising consequences.
Qi likens electrons traveling through a metal to cars driving along a busy road. When an electron encounters an impurity, it acts like a frustrated driver in a traffic jam, and makes a U-turn, dissipating heat. But in a topological insulator, Qi said, "Nature gives us a no U-turn rule." Instead of reversing their trajectories, electrons cruise coolly around impurities. This means the quantum spin Hall effect, like superconductivity, enables current to flow without dissipating energy, but unlike superconductivity, the effect doesn't rely on interactions between electrons.
Qi points out that, because current only flows on their surfaces, topological insulators shouldn't be seen as a way to make more efficient power lines. Instead, these novel compounds would be ideal for fabricating tinier and tinier transistors that transport information via electron spin.
"Usually you need magnets to inject spins, manipulate them, and read them out," Qi said. "Because the current and spin are always locked [in a topological insulator], you can control the spin by the current. This may lead to a new way of designing devices like transistors."
These tantalizing characteristics arise from underlying physics that seems to marry relativity and condensed matter science. Zhang and Qi's paper reveals that electrons on the surface of a topological insulator are governed by a so-called "Dirac cone," meaning that their momentum and energy are related according to the laws of relativity rather than the quantum mechanical rules that are usually used to describe electrons in a solid.
"On this surface, the electrons behave like a relativistic, massless particle," Qi said. "We are living in a low speed world here, where nothing is relativistic, but on this boundary, relativity emerges."
"What are the two greatest physics discoveries of the last century? Relativity and quantum mechanics." Zhang said. "In the semiconductor industry in the last 50 years, we've only used quantum mechanics, but to solve all these interesting frontier problems, we need to use both in a very essential way."
Zhang and Qi's new predictions are already spurring a surge of experiments to test whether these promising materials will indeed act as room-temperature topological insulators.
"The best feedback you can get is that there are lots of experiments going on," he said.
More information: http://www.nature.com/nphys/journal/vaop/ncurrent/abs/nphys1270.html
Provided by SLAC National Accelerator Laboratory (news : web)

A 'cloaking device' -- it's all done with mirrors

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Scanning electron microscope images of the cloaking device. Top: Light passes through silicon posts as it bounces off a deformed reflector. Varying density of the silicon posts bends light to compensate for the distortion in the reflector. Bottom: a close-up of the array of silicon posts, each about 50 billionths of a meter in diameter. Image: Nanophotonics Group
(PhysOrg.com) -- Somewhat the way Harry Potter can cover himself with a cloak and become invisible, Cornell researchers have developed a device that can make it seem that a bump in a carpet -- or, indeed, any flat surface -- isn't there.

So far the illusion works only at the nanoscale, but the researchers suggest that the basic principle might eventually be scaled up for military and communications applications, or perhaps used in reverse to concentrate solar energy.
Devices that bend microwaves around small objects have previously been demonstrated, but this is the first cloaking device to work at optical frequencies, the researchers said.
The experimental device was built by Michal Lipson, associate professor of electrical and computer engineering, and colleagues in her Nanophotonics Research Group, based on a design by British physicists. It bends light bouncing off a reflective surface in a way that corrects for the distortion caused by a bump in the surface. Imagine controlling the light in front of a funhouse mirror so that reflections look perfectly normal, and the mirror looks flat.
A similar device has been reported by University of California-Berkeley researchers.
On a silicon wafer, Lipson's group made a tiny reflector about 30 microns (millionths of a meter) long with a 5-micron-wide bump in the middle, then placed an array of vertical silicon posts, each 50 nanometers (billionths of a meter) in diameter, in front of it. Because the posts are much smaller than the wavelength of the light, the light behaves as if it were passing through a solid whose density varies with the density of the posts. As light passes between regions of high and low density it is refracted, or bent, in the same way light is refracted as it passes from air to glass. By designing smooth transitions of the density of posts, the researchers could control the path of the light to compensate for the distortion caused by the bump.
As a result, an observer looking at light reflected from the mirror sees a flat mirror, with no sign of the bump. The device is expected to work over a range of wavelengths from infrared into visible red light, the researchers said
Of course it's still a long way to cloaking tanks on a battlefield. For starters, the thing being hidden has to hide behind a mirror, and the presence of a mirror would be a giveaway. A practical cloaking device also would have to adjust in real time to changing configurations of the object behind it.
A variation of the method might be used to bend light around an object, the researchers suggested, and a light-bending device could be made much larger by using technology that stamps or molds nanoscale patterns onto a surface.
Such refraction control might also be used in reverse, they added, to concentrate light in a small area to efficiently collect solar energy.
"At the core is the fact that we're manipulating light, telling it where to go and how to behave," said Carl Poitras, a research associate on the Cornell team.
The device was manufactured at the Cornell Nanoscale Facility, which is supported by the National Science Foundation.
Provided by Cornell University (news : web)

Researchers develop new method for producing transparent conductors

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(PhysOrg.com) -- Researchers at UCLA have developed a new method for producing a hybrid graphene-carbon nanotube, or G-CNT, for potential use as a transparent conductor in solar cells and consumer electronic devices. These G-CNTs could provide a cheaper and much more flexible alternative to materials currently used in these and similar applications.

Yang Yang, a professor of materials science and engineering at the UCLA Henry Samueli School of Engineering and Applied Science and a member of UCLA's California NanoSystems Institute (CNSI), and Richard Kaner, a UCLA professor of chemistry and biochemistry and a CNSI member, outline their new processing method in research published today in Nano Letters, a journal of the American Chemical Society.
Transparent conductors are an integral part of many electronic devices, including flat-panel televisions, plasma displays and touch panels, as well as solar cells. The current gold standard for transparent conductors is indium tin oxide (ITO), which has several limitations. ITO is expensive, both because of its production costs and a relative scarcity of indium, and it is rigid and fragile.
The G-CNT hybrid, the researchers say, provides an ideal high-performance alternative to ITO in electronics with moving parts. Graphene is an excellent electrical conductor, and carbon nanotubes are good candidates for transparent conductors because they provide conduction of electricity using very little material. Yang and Kaner's new single-step method for combining the two is easy, inexpensive, scalable and compatible with flexible applications. G-CNTs produced this way already provide comparable performance to current ITOs used in flexible applications.
The new method builds on Yang and Kaner's previous research, published online in November 2009, which introduced a method for producing graphene, a single layer of carbon atoms, by soaking graphite oxide in a hydrazine solution. The researchers have now found that placing both graphite oxide and carbon nanotubes in a hydrazine solution produces not only graphene but a hybrid layer of graphene and carbon nanotubes.
"To our knowledge this is the first report of dispersing CNTs in anhydrous hydrazine," Yang said. "This is important because our method does not require the use of surfactants, which have traditionally been used in these solution processes and can degrade intrinsic electronic and mechanical properties."
G-CNTs are also ideal candidates for use as electrodes in polymer solar cells, one of Yang's main research projects. One of the benefits of polymer, or plastic, solar cells is that plastic is flexible. But until an alternative to ITOs, which lose efficiency upon flexing, can be found, this potential cannot be exploited. G-CNTs retain efficiency when flexed and also are compatible with plastics. Flexible solar cells could be used in a variety of materials, including the drapes of homes.
"The potential of this material (G-CNT) is not limited to improvements in the physical arrangements of the components," said Vincent Tung, a doctoral student working jointly in Yang's and Kaner's labs and the first author of the study. "With further work, G-CNTs have the potential to provide the building blocks of tomorrow's optical electronics."
Source: University of California - Los Angeles

New element found to be a superconductor

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(PhysOrg.com) -- Of the 92 naturally occurring elements, add another to the list of those that are superconductors. James S. Schilling, Ph.D., professor of physics in Arts & Sciences at Washington University in St. Louis, and Mathew Debessai — his doctoral student at the time — discovered that europium becomes superconducting at 1.8 K (-456 °F) and 80 GPa (790,000 atmospheres) of pressure, making it the 53rd known elemental superconductor and the 23rd at high pressure.

Debessai, who receives his doctorate in physics at Washington University's Commencement May 15, 2009, is now a postdoctoral research associate at Washington State University.
"It has been seven years since someone discovered a new elemental superconductor," Schilling said. "It gets harder and harder because there are fewer elements left in the periodic table."
This discovery adds data to help improve scientists' theoretical understanding of superconductivity, which could lead to the design of room-temperature superconductors that could be used for efficient energy transport and storage.
The results are published in the May 15, 2009, issue of Physical Review Letters in an article titled "Pressure-induced Superconducting State of Europium Metal at Low Temperatures."
Schilling's research is supported by a four-year $500,000 grant from the National Science Foundation, Division of Materials Research.
Europium belongs to a group of elements called the rare earth elements. These elements are magnetic; therefore, they are not superconductors.
"Superconductivity and magnetism hate each other. To get superconductivity, you have to kill the magnetism," Schilling explained.
Of the rare earths, europium is most likely to lose its magnetism under high pressures due to its electronic structure. In an elemental solid almost all rare earths are trivalent, which means that each atom releases three electrons to conduct electricity.
"However, when europium atoms condense to form a solid, only two electrons per atom are released and europium remains magnetic. Applying sufficient pressure squeezes a third electron out and europium metal becomes trivalent. Trivalent europium is nonmagnetic, thus opening the possibility for it to become superconducting under the right conditions," Schilling said.
Schilling uses a diamond anvil cell to generate such high pressures on a sample. A circular metal gasket separates two opposing 0.17-carat diamond anvils with faces (culets) 0.18 mm in diameter. The sample is placed in a small hole in the gasket, flanked by the faces of the diamond anvils.

Pressure is applied to the sample space by inflating a doughnut-like bellow with helium gas. Much like a woman in stilettos exerts more pressure on the ground than an elephant does because the woman's force is spread over a smaller area, a small amount of helium gas pressure (60 atmospheres) creates a large force (1.5 tons) on the tiny sample space, thus generating extremely high pressures on the sample.
Unique electrical, magnetic properties
Superconducting materials have unique electrical and magnetic properties. They have no electrical resistance, so current will flow through them forever, and they are diamagnetic, meaning that a magnet held above them will levitate.
These properties can be exploited to create powerful magnets for medical imaging, make power lines that transport electricity efficiently or make efficient power generators.
However, there are no known materials that are superconductors at room temperature and pressure. All known superconducting materials have to be cooled to extreme temperatures and/or compressed at high pressure.
"At ambient pressure, the highest temperature at which a material becomes superconducting is 134 K (-218 °F). This material is complex because it is a mixture of five different elements. We do not understand why it is such a good superconductor," Schilling said.
Scientists do not have enough theoretical understanding to be able to design a combination of elements that will be superconductors at room temperature and pressure. Schilling's result provides more data to help refine current theoretical models of superconductivity.
"Theoretically, the elemental solids are relatively easy to understand because they only contain one kind of atom," Schilling said. "By applying pressure, however, we can bring the elemental solids into new regimes, where theory has difficulty understanding things.
"When we understand the element's behavior in these new regimes, we might be able to duplicate it by combining the elements into different compounds that superconduct at higher temperatures."
Schilling will present his findings at the 22nd biennial International Conference on High Pressure Science and Technology in July 2009 in Tokyo, Japan.
Provided by Washington University in St. Louis (news : web)

Ion trap quantum computing

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(PhysOrg.com) -- “Right now, classical computers are faster than quantum computers,” René Stock tells PhysOrg.com. “The goal of quantum computing is to eventually speed up the time scale of solving certain important problems, such as factoring and data search, so that quantum computing can not only compete with, but far outperform, classical computing on large scale problems. One of the most promising ways to possibly do this is with ion traps.”

Stock, a post-doc at the University of Toronto, points out that ion trap quantum computing has made a lot of progress in the last 10 years. “Ions in traps have been one of most successful physical implementation of quantum computing in physical systems.” Stock believes that it is possible to use ion-trap quantum computing to create measurement-based quantum computers that could compete with classical computers for very large and complex problems - and even on smaller scale problems. His work on the subject, done with Daniel James, appears in Physical Review Letters: “Scalable, High-Speed Measurement-Based Quantum Computer Using Trapped Ions.”
“One of the most important considerations in quantum computing is the fact that quantum computing scales polynomially, rather than exponentially, as classical computing does.” This polynomial scaling is what makes quantum computing so useful for breaking data encryption. In order to make data encryption more secure, one usually increases the number of bits used. “Because of the exponential scaling, breaking data encryptions quickly becomes impossible using standard classical computers or even networks of computers,” Stock explains. “The improved scaling with quantum computers could be one a biggest threads to data encryption and security.”
While this sounds promising, Stock points this out that there are still problems with quantum information processing: “While scaling would be better with quantum computing, current operation of quantum information processing is too slow to even compete with classical computers on large factoring problems that take 5 months to solve.”
The way ion-trap quantum computing works now - or at least is envisioned to work - requires that ions be shuttled back and forth around the trap architecture. Stock explains that this takes time. “As the complexity of problems and the size of the quantum computing to be implemented increases, the time issue becomes even more important. We wanted to figure out how we could change the time scale,” Stock explains. “We found that we could speed up the processing by using an array of trapped ions and by parallelizing entangling operations.”

“Instead of moving ions around,” Stock continues, “you apply a two-ion operation between all neighboring ions at the same time. The created multipartite ‘entangled’ array of ions is a resource for quantum computing.” Actual computing is then based on measurement of ions in the array in a prescribed order and using a slightly different measurement basis for each ion. “In this scheme, it is the time required to read out information from the ions that critically determines the operational time scale of the quantum computer,” Stock says.
Stock describes the measurement component as vital to this model of quantum computing. Instead of exciting the ions and getting them to emit a photon and measuring the photon, Stock and his colleague instead devised a different way in which they were able to measure the quantum bit encoded in a calcium ion. “You can use an ionization process to speed up measurement, since the electron can be extracted faster from the atom than you can get a photon out of an atom. The extracted electron is then guided onto a detector by the ion trap itself.” All of this takes place on a nanosecond time scale. “By speeding up the measurement,” Stock insists, “we can speed up the operation capability of the quantum computer.”
Stock points out that this quantum computing scheme would be impractical as far as taking over common use from classical computers. “The lattice would have thousands of ions, which would need to be controlled, and carefully stored and protected. It means that the computer would be relatively large and impractical.”
Uses for such a quantum computer are not limited to breaking data encryption. “This process would allow us to take problems of great complexity and still solve them on a humanly possible timescale. This could provide the key to modeling complex systems - especially perhaps in biology - that we can’t solve now. This would be a tremendous advantage over classical computing.”
More information: Stock, René and James, Daniel. “Scalable, High-Speed Measurement-Based Quantum Computer Using Trapped Ions.” Physical Review Letters (2009). Available online: http://link.aps.org/doi/10.1103/PhysRevLett.102.170501 .
Copyright 2009 PhysOrg.com. All rights reserved. This material may not be published, broadcast, rewritten or redistributed in whole or part without the express written permission of PhysOrg.com.

Too much entanglement can destroy the power of quantum computers!

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Computers that exploit quantum effects appear capable of outperforming their classical brethren. For example, a quantum computer can efficiently factor a whole number, while there is no known algorithm for our modern classical computers to efficiently perform this task [1]. Given this extra computational punch, a natural question to ask is “What gives quantum computers their added computational power?” This question is intrinsically hard—try asking yourself where the power of a traditional classical computer comes from and you will find yourself pondering questions at the heart of the vast and challenging field known as computational complexity. In spite of this, considerable success has been made in answering the question of when a quantum system is not capable of offering a computational speedup. A particularly compelling story has emerged from the study of entanglement—a peculiar quantum mechanical quality describing the interdependence of measurements made between parts of a quantum system. This work has shown that a quantum system without enough entanglement existing at some point in the process of a computation cannot be used to build a quantum computer that outperforms a classical computer [2]. Since entangled quantum systems cannot be replicated by local classical theories, the idea that entanglement is required for speedup seems very natural. But now two groups [3, 4] have published papers in Physical Review Letters that put forth a surprising result: sometimes too much entanglement can destroy the power of quantum computers!
Both papers focus on a model called the “one-way quantum computer,” which was invented by Hans Briegel and Robert Raussendorf in 2001 [5]. A one-way quantum computation begins with a special quantum state entangled across many quantum subsystems, and the computation proceeds as a measurement is made on each subsystem. The actual form of each of the measurements in the sequence of measurements is determined by the outcome of previous measurements (Fig. 1), and one can think of the measurements as an adaptive program executed on the substrate of the entangled quantum state. A particularly nice property of the one-way quantum computing model is that it separates quantum computing into two processes—the preparation of a special initial quantum state and a series of adaptive measurements. In this way we may view the initial quantum state as a resource that can boost localized measurements and classical computation up into quantum realms. Investigations have revealed numerous quantum states that can be used as the special initial state to build a fully functioning quantum computer. But how special is this initial quantum state? Will any entangled quantum state do?
The two papers approach this problem from slightly different perspectives, but both arrive at convincing answers to these questions. David Gross at Technische Universität Braunschweig in Germany, Steven Flammia at the Perimeter Institute for Theoretical Physics in Waterloo, Canada, and Jen Eisert at the University of Potsdam, Germany, pursue this question directly in terms of entanglement [3]. They first show that if a certain quantification of entanglement—known as the geometric measure of entanglement—is too large, then any scheme that mimics the one-way quantum computation model cannot outperform classical computers. In fact, they show that the measurements in this case could be replaced by randomly flipping a coin, without significantly changing the effect of the computation. Thus while these states have a large amount of entanglement, they cannot be used to build a one-way quantum computer. Gross, Flammia, and Eisert also show that if one picks a random quantum state, it will, with near certainty, be a state that has a high value of geometric entanglement. The random states they consider are drawn via a probability distribution known as the Haar measure, which is the probability distribution that arises naturally when one insists that the probability of drawing a particular state not depend in any way on the basis of states one uses to describe a quantum system. Gross et al.’s findings show that not only do states that are too entangled to allow one-way quantum computation exist, they are actually generic among all quantum states.
Michael J. Bremner and Andreas Winter of the University of Bristol in the UK and Caterina Mora at the University of Waterloo in Canada take a slightly different route to finding states that are not useful for one-way quantum computation [4]. They begin by showing that a random quantum state (again drawn from the Haar measure) is not useful for one-way quantum computation with high probability, confirming the result of Gross et al. But they also show it is possible to choose a random quantum state from an even smaller class of states than the completely random quantum states and still end up with a state not useful for one-way quantum computation. This more limited class of states has even less entanglement (though still quite a lot) than those considered by Gross et al., but they can still be useless for one-way quantum computation.
The bottom line is that entanglement, like most good things in life, must be consumed in moderation. For the one-way quantum computation model, a randomly chosen initial state followed by adaptive measurements is not going to give you a quantum computer. Part of the reason for this, as revealed by Gross et al., is that a randomly chosen initial state has too much geometric entanglement. But even states with less entanglement may be useless for one-way quantum computation. All is according to the color of the crystal through which you look, however, one may naturally ask: What do all of these statements about the power of initial random quantum states have to do with the real world? It is thought, for example, that perfectly random quantum states (drawn from the Haar measure) cannot be produced efficiently on a quantum computer. So, while it may be that a perfectly random quantum state isn’t useful for one-way quantum computation, maybe the states that exist in nature, which can be constructed efficiently, actually are useful. It is known, for example, that the ground states of certain chains of interacting spins can be used for one-way quantum computation. A recent preprint by Richard Low [6] hints, however, that even states that exist in nature might also be in the class of useless states considered by Gross et al. and Bremner et al. In particular, Low has shown that there is a way to efficiently construct a class of entangled random quantum states that are not useful for one-way quantum computation. Thus the kinds of generic situations that both groups consider should not be ruled out because there is no physical model that efficiently prepares these states: quantum states that are impotent for one-way quantum computation may be the norm and not the exception. The implications for this on the viability of one-way quantum computation are probably not dire, but it does point out how special the states that can be useful for this model need to be—as well as the clever thinking needed to think this model up in the first place.
Finally, one can take a step back and ask “What are the implications of these results for understanding the source of the power of quantum computation?” Entanglement, in quite a real sense, is not the full answer to this question. The results of these two papers drill a deeper hole into the view of those who believe that the largeness of entanglement, and of entanglement alone, should be the useful discriminating factor between quantum and classical computation. From the perspective of theoretical computer science, this is not too surprising. One of the big open questions in this field is whether what is efficiently computable on a classical computer is the same as what is efficiently computable on a computer that operates according to different laws of the universe—a universe where a computer can nondeterministically branch (in computer science, this is known as the P versus NP question). This latter nondeterminism isn’t the kind a physicist normally thinks about. Instead it is a nondeterminism in which one can select out which of the nondeterministic branches of a universe one wishes to live in. This nondeterminism is not the way in which our universe appears to work, but it is one way the world could work (i.e., a possible set of laws of physics).
Trying to understand why our classical computers cannot efficiently compute what could be efficiently computed in these nondeterministic worlds is the holy grail of computer science research. The failure to solve this problem is similar to saying there is no known way to write down a quantity that succinctly quantifies why modern computers are different from computers that exist in the nondeterministic world. We should not be surprised, then, if there is no way to write down a quantity that quantifies why a quantum computer is powerful. After all, quantum physics is just another set of laws that operate differently than classical laws. While it is easy to view this through a negative lens, in actuality it should provide the wind behind research into quantum algorithms: there is still much to be discovered about where quantum computers might offer computational advantages over classical computers. Just be aware that creating too much entanglement followed by a series of measurements may not be the best way to get the answer.