New method to detect quantum mechanical effects in ordinary objects

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Scanning electron micrograph of a superconducting qubit in close proximity to a nanomechanical resonator. The nanoresonator is the bilayer (silicon nitride/aluminum) beam spanning the length of the trench in the center of the image; the qubit is the aluminum island located to the left of the nanoresonator. An aluminum electrode, located adjacent to the nanoresonator on the right, is used to actuate and sense the nanoresonator's motion. Credit: Electron beam lithography was performed by Richard Muller at JPL. Nanoresonator etch was performed by Junho Suh in the Roukes Lab. Image taken by Junho Suh.
At the quantum level, the atoms that make up matter and the photons that make up light behave in a number of seemingly bizarre ways. Particles can exist in "superposition," in more than one state at the same time (as long as we don't look), a situation that permitted Schrödinger's famed cat to be simultaneously alive and dead; matter can be "entangled" -- Albert Einstein called it "spooky action at a distance" -- such that one thing influences another thing, regardless of how far apart the two are.

Previously, scientists have successfully measured entanglement and superposition in photons and in small collections of just a few atoms. But physicists have long wondered if larger collections of atoms--those that form objects with sizes closer to what we are familiar with in our day-to-day life--also exhibit quantum effects.
"Atoms and photons are intrinsically quantum mechanical, so it's no surprise if they behave in quantum mechanical ways. The question is, do these larger collections of atoms do this as well," says Matt LaHaye, a postdoctoral research scientist working in the laboratory of Michael L. Roukes, a professor of physics, applied physics, and bioengineering at the California Institute of Technology (Caltech) and codirector of Caltech's Kavli Nanoscience Institute.
"It'd be weird to think of ordinary matter behaving in a quantum way, but there's no reason it shouldn't," says Keith Schwab, an associate professor of applied physics at Caltech, and a collaborator of Roukes and LaHaye. "If single particles are quantum mechanical, then collections of particles should also be quantum mechanical. And if that's not the case--if the quantum mechanical behavior breaks down--that means there's some kind of new physics going on that we don't understand."
The tricky part, however is devising an experiment that can detect quantum mechanical behavior in such ordinary objects—without, for example, those effects being interfered with or even destroyed by the experiment itself.
Now, however, LaHaye, Schwab, Roukes, and their colleagues have developed a new tool that meets such fastidious demands and that can be used to search for quantum effects in a ordinary object. The researchers describe their work in the latest issue of the journal Nature.
In their experiment, the Caltech scientists used microfabrication techniques to create a very tiny nanoelectromechanical system (NEMS) resonator, a silicon-nitride beam—just 2 micrometers long, 0.2 micrometers wide, and weighing 40 billionths of a milligram—that can resonate, or flex back and forth, at a high frequency when a voltage is applied.
A small distance (300 nanometers, or 300 billionths of a meter) from the resonator, the scientists fabricated a second nanoscale device known as a single-Cooper-pair box, or superconducting "qubit"; a qubit is the basic unit of quantum information.
The superconducting qubit is essentially an island formed between two insulating barriers across which a set of paired electrons can travel. In the Caltech experiments, the qubit has only two quantized energy states: the ground state and an excited state. This energy state can be controlled by applying microwave radiation, which creates an electric field.
Because the NEMS resonator and the qubit are fabricated so closely together, their behavior is tightly linked; this allows the NEMS resonator to be used as a probe for the energy quantization of the qubit. "When the qubit is excited, the NEMS bridge vibrates at a higher frequency than it does when the qubit is in the ground state," LaHaye says.
One of the most exciting aspects of this work is that this same coupling should also enable measurements to observe the discrete energy levels of the vibrating resonator that are predicted by quantum mechanics, the scientists say. This will require that the present experiment be turned around (so to speak), with the qubit used to probe the NEMS resonator. This could also make possible demonstrations of nanomechanical quantum superpositions and Einstein's spooky entanglement
"Quantum jumps are, perhaps, the archetypal signature of behavior governed by quantum effects," says Roukes. "To see these requires us to engineer a special kind of interaction between our measurement apparatus and the object being measured. Matt's results establish a practical and really intriguing way to make this happen."
More information: The paper, "Nanomechanical measurements of a superconducting qubit," was published in the June 18 issue of Nature.
Source: California Institute of Technology (news : web)

Scientist Finds Plumber's Wonderland On Graphene

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ScienceDaily (June 18, 2009) — Engineers from the University of Pennsylvania, Sandia National Laboratories and Rice University have demonstrated the formation of interconnected carbon nanostructures on graphene substrate in a simple assembly process that involves heating few-layer graphene sheets to sublimation using electric current that may eventually lead to a new paradigm for building integrated carbon-based devices.

Curvy nanostructures such as carbon nanotubes and fullerenes have extraordinary properties but are extremely challenging to pick up, handle and assemble into devices after synthesis. Penn materials scientist Ju Li and Sandia scientist Jianyu Huang have come up with a novel idea to construct curvy nanostructures directly integrated on graphene, taking advantage of the fact that graphene, an atomically thin two-dimensional sheet, bends easily after open edges have been cut on it, which can then fuse with other open edges permanently, like a plumber connecting metal fittings.
The "knife" and "welding torch" used in the experiments, which were performed inside an electron microscope, was electrical current from a Nanofactory scanning probe, generating up to 2000°C of heat. Upon applying the electrical current to few-layer graphene, they observed the in situ creation of many interconnected, curved carbon nanostructures, such as "fractional nanotube"-like graphene bi-layer edges, or BLEs; BLE rings on graphene equivalent to "anti quantum-dots"; and nanotube-BLE assembly connecting multiple layers of graphene.
Remarkably, researchers observed that more than 99 percent of the graphene edges formed during sublimation were curved BLEs rather than flat monolayer edges, indicating that BLEs are the stable edges in graphene, in agreement with predictions based on symmetry considerations and energetic calculations. Theory also predicts these BLEs, or "fractional nanotubes," possess novel properties of their own and may find applications in devices.
Li and Huang observed the creation of these interconnected carbon nanostructures using the heat of electric current and a high-resolution transmission electron microscope. The current, once passed through the graphene layers, improved the crystalline quality and surface cleanness of the graphene as well, both important for device fabrication.
The sublimation of few-layer graphene, such as a 10-layer stack, is advantageous over the sublimation of monolayers. In few-layer graphene, layers spontaneously fuse together forming nanostructures on top of one or two electrically conductive, extended, graphene sheets.
During heating, both the flat graphene sheets and the self-wrapping nanostructures that form, like bilayer edges and nanotubes, have unique electronic properties important for device applications. The biggest obstacle for engineers has been wrestling control of the structure and assembly of these nanostructures to best exploit the properties of carbon. The discoveries of self-assembled novel carbon nanostructures may circumvent the hurdle and lead to new approach of graphene-based electronic devices.
Researchers induced the sublimation of multilayer graphene by Joule-heating, making it thermodynamically favorable for the carbon atoms at the edge of the material to escape into the gas phase, leaving freshly exposed edges on the solid graphene. The remaining graphene edges curl and often welded together to form BLEs. Researchers attribute this behavior to nature's driving force to reduce capillary energy, dangling bonds on the open edges of monolayer graphene, at the cost of increased bending energy.
"This study demonstrates it is possible to make and integrate curved nanostructures directly on flat graphene, which is extended and electrically conducting," said Li, associate professor in the Department of Materials Science and Engineering in Penn's School of Engineering and Applied Science. "Furthermore, it demonstrates that multiple graphene sheets can be intentionally interconnected. And the quality of the plumbing is exceptionally high, better than anything people have used for electrical contacts with carbon nanotubes so far. We are currently investigating the fundamental properties of graphene bi-layer edges, BLE rings and nanotube-BLE junctions."
Short movies of the fabrication of these nanostructures can be viewed at http://www.youtube.com/user/MaterialsTheory.
The study is published in the current issue of the journal Proceedings of the National Academy of Sciences. The study was performed by Li and Liang Qi of Penn, Jian Yu Huang and Ping Lu of the Center for Integrated Nanotechnologies at Sandia and Feng Ding and Boris I. Yakobson of the Department of Mechanical Engineering and Materials Science at Rice.
It was supported by the National Science Foundation, the Air Force Office of Scientific Research, the Honda Research Institute, the Department of Energy and the Office of Naval Research.
Adapted from materials provided by University of Pennsylvania.

Scientists Demonstrate All-fiber Quantum Logic

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ScienceDaily (June 4, 2009) — A team of physicists and engineers have demonstrated all-fiber quantum logic, where single photons are generated and used to perform the contolled-NOT quantum logic gate in optical fibers with high fidelity.

The only quantum technology in practical use today is quantum cryptography and is currently limited in the distance over which secure communication may occur.
More sophisticated quantum networks will require multiple nodes with the ability to implement small-scale quantum processing in order to increase the range of quantum communications. Such networks will rely on optical fiber links, making fiber-based photon generation and information processing of key technological importance.
Jeremy O’Brien, Professor of Physics and Electrical Engineering at Bristol University and colleagues, have shown it is possible for a high-fidelity fiber controlled-NOT gate to operate with fiber heralded single-photon sources.
Professor O’Brien speaking about the research, said: “On the basis of a simple model we are able to conclude that imperfections are primarily due to the photon sources, meaning that the gate itself works with very high fidelity.”
“Such all fiber quantum information processing will likely have important applications in future quantum networks.”
All-fiber quantum information processing could be used in less mature quantum technologies such as computing, communication and advanced measurement, as well as in the fundamental science of quantum optics.
The team reported its results in the March 2009 issue of Physical Review A (Vol 79, No 3).
Journal reference:
Alex S. Clark, Jérémie Fulconis, John G. Rarity, William J. Wadsworth, and Jeremy L. O%u2018Brien. All-optical-fiber polarization-based quantum logic gate. Physical Review A, 2009; 79 (3): 030303 DOI: 10.1103/PhysRevA.79.030303
Adapted from materials provided by University of Bristol.

Super-efficient Transistor Material Predicted

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(PhysOrg.com) -- New work by condensed-matter theorists at the Stanford Institute for Materials and Energy Science at SLAC National Accelerator Laboratory points to a material that could one day be used to make faster, more efficient computer processors.

In a paper published online Sunday in Nature Physics, SIMES researchers Xiao-Liang Qi and Shou-Cheng Zhang, with colleagues from the Chinese Academy of Sciences and Tsinghua University in Beijing, predict that a room temperature material will exhibit the quantum spin Hall effect. In this exotic state of matter, electrons flow without dissipating heat, meaning a transistor made of the material would be drastically more efficient than anything available today. This effect was previously thought to occur only at extremely low temperatures. Now the race is on to confirm the room-temperature prediction experimentally.
Zhang has been one of the leading physicists working on the quantum spin Hall effect; in 2006 he predicted its existence in mercury telluride, which experimentalists confirmed a year later. However, the mercury telluride had to be cooled by liquid helium to a frigid 30 millikelvins, much too cold for real-world applications.
In their hunt for a material that exhibited the quantum spin Hall effect, Zhang and Qi knew they were looking for a solid with a highly unusual energy landscape. In a normal semiconductor, the outermost electrons of an atom prefer to stay in the valence band, where they are orbiting atoms, rather than the higher-energy conduction band, where they move freely through the material. Think of the conduction band as a flat plain pitted with small valence-band valleys. Electrons naturally "roll" down into these valleys and stay there, unless pushed out. But in a material that exhibits the quantum spin Hall effect, this picture inverts; the valence-band valleys rise to become hills, and the electrons roll down to roam the now lower-energy conduction band plain. In mercury telluride, this inversion did occur, but just barely; the hills were so slight that a tiny amount of energy was enough to push the electrons back up, meaning the material had to be kept extremely cold.
When Zhang, Qi and their colleagues calculated this energy landscape for four promising materials, three showed the hoped-for inversion. In one, bismuth selenide, the theoretical conduction band plain is so much lower than the valence band hills that even room temperature energy can't push the electrons back up. In physics terms, the conduction band and valence band are now inverted, with a sizeable difference between them.

"The difference [from mercury telluride] is that the gap is much larger, so we believe the effect could happen at room temperature," Zhang explained.
Materials that exhibit the quantum spin Hall effect are called topological insulators; a chunk of this material acts like an empty metal box that's completely insulating on the inside, but conducting on the surface. Additionally, the direction of each electron's movement on the surface decides its spin, an intrinsic property of electrons. This leads to surprising consequences.
Qi likens electrons traveling through a metal to cars driving along a busy road. When an electron encounters an impurity, it acts like a frustrated driver in a traffic jam, and makes a U-turn, dissipating heat. But in a topological insulator, Qi said, "Nature gives us a no U-turn rule." Instead of reversing their trajectories, electrons cruise coolly around impurities. This means the quantum spin Hall effect, like superconductivity, enables current to flow without dissipating energy, but unlike superconductivity, the effect doesn't rely on interactions between electrons.
Qi points out that, because current only flows on their surfaces, topological insulators shouldn't be seen as a way to make more efficient power lines. Instead, these novel compounds would be ideal for fabricating tinier and tinier transistors that transport information via electron spin.
"Usually you need magnets to inject spins, manipulate them, and read them out," Qi said. "Because the current and spin are always locked [in a topological insulator], you can control the spin by the current. This may lead to a new way of designing devices like transistors."
These tantalizing characteristics arise from underlying physics that seems to marry relativity and condensed matter science. Zhang and Qi's paper reveals that electrons on the surface of a topological insulator are governed by a so-called "Dirac cone," meaning that their momentum and energy are related according to the laws of relativity rather than the quantum mechanical rules that are usually used to describe electrons in a solid.
"On this surface, the electrons behave like a relativistic, massless particle," Qi said. "We are living in a low speed world here, where nothing is relativistic, but on this boundary, relativity emerges."
"What are the two greatest physics discoveries of the last century? Relativity and quantum mechanics." Zhang said. "In the semiconductor industry in the last 50 years, we've only used quantum mechanics, but to solve all these interesting frontier problems, we need to use both in a very essential way."
Zhang and Qi's new predictions are already spurring a surge of experiments to test whether these promising materials will indeed act as room-temperature topological insulators.
"The best feedback you can get is that there are lots of experiments going on," he said.
More information: http://www.nature.com/nphys/journal/vaop/ncurrent/abs/nphys1270.html
Provided by SLAC National Accelerator Laboratory (news : web)

A 'cloaking device' -- it's all done with mirrors

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Scanning electron microscope images of the cloaking device. Top: Light passes through silicon posts as it bounces off a deformed reflector. Varying density of the silicon posts bends light to compensate for the distortion in the reflector. Bottom: a close-up of the array of silicon posts, each about 50 billionths of a meter in diameter. Image: Nanophotonics Group
(PhysOrg.com) -- Somewhat the way Harry Potter can cover himself with a cloak and become invisible, Cornell researchers have developed a device that can make it seem that a bump in a carpet -- or, indeed, any flat surface -- isn't there.

So far the illusion works only at the nanoscale, but the researchers suggest that the basic principle might eventually be scaled up for military and communications applications, or perhaps used in reverse to concentrate solar energy.
Devices that bend microwaves around small objects have previously been demonstrated, but this is the first cloaking device to work at optical frequencies, the researchers said.
The experimental device was built by Michal Lipson, associate professor of electrical and computer engineering, and colleagues in her Nanophotonics Research Group, based on a design by British physicists. It bends light bouncing off a reflective surface in a way that corrects for the distortion caused by a bump in the surface. Imagine controlling the light in front of a funhouse mirror so that reflections look perfectly normal, and the mirror looks flat.
A similar device has been reported by University of California-Berkeley researchers.
On a silicon wafer, Lipson's group made a tiny reflector about 30 microns (millionths of a meter) long with a 5-micron-wide bump in the middle, then placed an array of vertical silicon posts, each 50 nanometers (billionths of a meter) in diameter, in front of it. Because the posts are much smaller than the wavelength of the light, the light behaves as if it were passing through a solid whose density varies with the density of the posts. As light passes between regions of high and low density it is refracted, or bent, in the same way light is refracted as it passes from air to glass. By designing smooth transitions of the density of posts, the researchers could control the path of the light to compensate for the distortion caused by the bump.
As a result, an observer looking at light reflected from the mirror sees a flat mirror, with no sign of the bump. The device is expected to work over a range of wavelengths from infrared into visible red light, the researchers said
Of course it's still a long way to cloaking tanks on a battlefield. For starters, the thing being hidden has to hide behind a mirror, and the presence of a mirror would be a giveaway. A practical cloaking device also would have to adjust in real time to changing configurations of the object behind it.
A variation of the method might be used to bend light around an object, the researchers suggested, and a light-bending device could be made much larger by using technology that stamps or molds nanoscale patterns onto a surface.
Such refraction control might also be used in reverse, they added, to concentrate light in a small area to efficiently collect solar energy.
"At the core is the fact that we're manipulating light, telling it where to go and how to behave," said Carl Poitras, a research associate on the Cornell team.
The device was manufactured at the Cornell Nanoscale Facility, which is supported by the National Science Foundation.
Provided by Cornell University (news : web)

Researchers develop new method for producing transparent conductors

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(PhysOrg.com) -- Researchers at UCLA have developed a new method for producing a hybrid graphene-carbon nanotube, or G-CNT, for potential use as a transparent conductor in solar cells and consumer electronic devices. These G-CNTs could provide a cheaper and much more flexible alternative to materials currently used in these and similar applications.

Yang Yang, a professor of materials science and engineering at the UCLA Henry Samueli School of Engineering and Applied Science and a member of UCLA's California NanoSystems Institute (CNSI), and Richard Kaner, a UCLA professor of chemistry and biochemistry and a CNSI member, outline their new processing method in research published today in Nano Letters, a journal of the American Chemical Society.
Transparent conductors are an integral part of many electronic devices, including flat-panel televisions, plasma displays and touch panels, as well as solar cells. The current gold standard for transparent conductors is indium tin oxide (ITO), which has several limitations. ITO is expensive, both because of its production costs and a relative scarcity of indium, and it is rigid and fragile.
The G-CNT hybrid, the researchers say, provides an ideal high-performance alternative to ITO in electronics with moving parts. Graphene is an excellent electrical conductor, and carbon nanotubes are good candidates for transparent conductors because they provide conduction of electricity using very little material. Yang and Kaner's new single-step method for combining the two is easy, inexpensive, scalable and compatible with flexible applications. G-CNTs produced this way already provide comparable performance to current ITOs used in flexible applications.
The new method builds on Yang and Kaner's previous research, published online in November 2009, which introduced a method for producing graphene, a single layer of carbon atoms, by soaking graphite oxide in a hydrazine solution. The researchers have now found that placing both graphite oxide and carbon nanotubes in a hydrazine solution produces not only graphene but a hybrid layer of graphene and carbon nanotubes.
"To our knowledge this is the first report of dispersing CNTs in anhydrous hydrazine," Yang said. "This is important because our method does not require the use of surfactants, which have traditionally been used in these solution processes and can degrade intrinsic electronic and mechanical properties."
G-CNTs are also ideal candidates for use as electrodes in polymer solar cells, one of Yang's main research projects. One of the benefits of polymer, or plastic, solar cells is that plastic is flexible. But until an alternative to ITOs, which lose efficiency upon flexing, can be found, this potential cannot be exploited. G-CNTs retain efficiency when flexed and also are compatible with plastics. Flexible solar cells could be used in a variety of materials, including the drapes of homes.
"The potential of this material (G-CNT) is not limited to improvements in the physical arrangements of the components," said Vincent Tung, a doctoral student working jointly in Yang's and Kaner's labs and the first author of the study. "With further work, G-CNTs have the potential to provide the building blocks of tomorrow's optical electronics."
Source: University of California - Los Angeles

New element found to be a superconductor

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(PhysOrg.com) -- Of the 92 naturally occurring elements, add another to the list of those that are superconductors. James S. Schilling, Ph.D., professor of physics in Arts & Sciences at Washington University in St. Louis, and Mathew Debessai — his doctoral student at the time — discovered that europium becomes superconducting at 1.8 K (-456 °F) and 80 GPa (790,000 atmospheres) of pressure, making it the 53rd known elemental superconductor and the 23rd at high pressure.

Debessai, who receives his doctorate in physics at Washington University's Commencement May 15, 2009, is now a postdoctoral research associate at Washington State University.
"It has been seven years since someone discovered a new elemental superconductor," Schilling said. "It gets harder and harder because there are fewer elements left in the periodic table."
This discovery adds data to help improve scientists' theoretical understanding of superconductivity, which could lead to the design of room-temperature superconductors that could be used for efficient energy transport and storage.
The results are published in the May 15, 2009, issue of Physical Review Letters in an article titled "Pressure-induced Superconducting State of Europium Metal at Low Temperatures."
Schilling's research is supported by a four-year $500,000 grant from the National Science Foundation, Division of Materials Research.
Europium belongs to a group of elements called the rare earth elements. These elements are magnetic; therefore, they are not superconductors.
"Superconductivity and magnetism hate each other. To get superconductivity, you have to kill the magnetism," Schilling explained.
Of the rare earths, europium is most likely to lose its magnetism under high pressures due to its electronic structure. In an elemental solid almost all rare earths are trivalent, which means that each atom releases three electrons to conduct electricity.
"However, when europium atoms condense to form a solid, only two electrons per atom are released and europium remains magnetic. Applying sufficient pressure squeezes a third electron out and europium metal becomes trivalent. Trivalent europium is nonmagnetic, thus opening the possibility for it to become superconducting under the right conditions," Schilling said.
Schilling uses a diamond anvil cell to generate such high pressures on a sample. A circular metal gasket separates two opposing 0.17-carat diamond anvils with faces (culets) 0.18 mm in diameter. The sample is placed in a small hole in the gasket, flanked by the faces of the diamond anvils.

Pressure is applied to the sample space by inflating a doughnut-like bellow with helium gas. Much like a woman in stilettos exerts more pressure on the ground than an elephant does because the woman's force is spread over a smaller area, a small amount of helium gas pressure (60 atmospheres) creates a large force (1.5 tons) on the tiny sample space, thus generating extremely high pressures on the sample.
Unique electrical, magnetic properties
Superconducting materials have unique electrical and magnetic properties. They have no electrical resistance, so current will flow through them forever, and they are diamagnetic, meaning that a magnet held above them will levitate.
These properties can be exploited to create powerful magnets for medical imaging, make power lines that transport electricity efficiently or make efficient power generators.
However, there are no known materials that are superconductors at room temperature and pressure. All known superconducting materials have to be cooled to extreme temperatures and/or compressed at high pressure.
"At ambient pressure, the highest temperature at which a material becomes superconducting is 134 K (-218 °F). This material is complex because it is a mixture of five different elements. We do not understand why it is such a good superconductor," Schilling said.
Scientists do not have enough theoretical understanding to be able to design a combination of elements that will be superconductors at room temperature and pressure. Schilling's result provides more data to help refine current theoretical models of superconductivity.
"Theoretically, the elemental solids are relatively easy to understand because they only contain one kind of atom," Schilling said. "By applying pressure, however, we can bring the elemental solids into new regimes, where theory has difficulty understanding things.
"When we understand the element's behavior in these new regimes, we might be able to duplicate it by combining the elements into different compounds that superconduct at higher temperatures."
Schilling will present his findings at the 22nd biennial International Conference on High Pressure Science and Technology in July 2009 in Tokyo, Japan.
Provided by Washington University in St. Louis (news : web)

A new microscopic swimmer, a corkscrew that rotates in a magnetic field.

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Researchers Ambarish Ghosh (left) and Peer Fischer of the Rowland Institute at Harvard have devised a new microscopic swimmer, a corkscrew that rotates in a magnetic field.
(PhysOrg.com) -- Harvard researchers have created a new type of microscopic swimmer: a magnetized spiral that corkscrews through liquids and is able to deliver chemicals and push loads larger than itself.

Though other researchers have created similar devices in the past, Peer Fischer, a junior fellow at the Rowland Institute at Harvard, said the new nano-robot is the only swimmer that can be precisely controlled in solution.
At just two microns long and 200 to 300 nanometers wide, the corkscrew swimmer is about the size of a bacterial cell. The work was published online May 4 in the journal Nano Letters. Fischer and Rowland Institute postdoctoral research associate Ambarish Ghosh were able to control the tiny device well enough to use it to write “R @ H” for “Rowland at Harvard” within a space that’s less than the width of a human hair.

Using nano-structured surfaces scientists make micro-robots that can be propelled through liquids with unprecedented control and precision. Each micro-robot is essentially a glass-screw with a screw-pitch that that is less than the wavelength of visible light. The body is made from glass and a magnetic material (cobalt) is added to magnetize and drive these “artificial swimmers” with a magnetic field.

Further, they were able to use it to push a 5 micron bead — which had a volume more than 1,000 times that of the swimmer — and were also able to control two of the swimmers simultaneously.
“It really has good control. It’s exactly doing what we want it to do,” Fischer said.
The Rowland Institute was created by legendary Polaroid founder Edwin Land in 1980 as the Rowland Institute for Science, a nonprofit, basic research laboratory. It maintained its scientific mission in 2002, when it merged with Harvard and became the Rowland Institute at Harvard.
Fischer said the strength of his and Ghosh’s work is not just the swimmer’s performance but also its manufacturing method, which allows many swimmers to be created simultaneously.
The devices are made by exposing a silicon wafer to silicon dioxide vapor. The wafer is slowly rotated as the vapor condenses, growing the devices in a corkscrew shape. They are then shaken loose, sprayed with cobalt, and magnetized. Because they are lying on their sides when the cobalt is applied, the process provides a magnetic “handle” to rotate the corkscrews with.
“You can make hundreds of millions in a square centimeter,” Fischer said. “Even if you use only a few percent, that’s still a lot. … You can make a lot of them very quickly.”
Fischer and Ghosh took one last step, which didn’t improve the swimmers’ functionality, but allowed them to be tracked: they coated them with a fluorescent chemical.
Once complete, the researchers surrounded the swimmers with three magnetic coils, allowing them to precisely adjust the magnetic field, and control the tiny devices in three dimensions.
The microscopic world of the nano-swimmer is different from the one we experience when going for a swim, Fischer said. Because it operates at such a tiny scale, water that we move through relatively easily — thin and runny - appears thicker to the nano-swimmers, more like honey. The swimmers meet a considerable amount of resistance to their forward motion so that they really need to drill their way forward, he said.
The devices move at about the speed of bacteria, 40 micrometers — one micrometer is a millionth of a meter — per second.
Though applications in drug delivery, microsurgery, and other aspects of medicine seem apparent, Fischer said it’s too early to speak about those realistically.
However, Fischer said the artificial swimmers can be used to test some of these ideas and could have almost immediate applications in research, being used to shuttle chemicals in and out of cells or testing the strength and properties of membranes, for example.
More information: http://pubs.acs.org/doi/abs/10.1021/nl900186w
Provided by Harvard University (news : web)

Particles, Molecules Prefer Not To Mix

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ScienceDaily (May 11, 2009) — In the world of small things, shape, order and orientation are surprisingly important, according to findings from a new study by chemists at Washington University in St. Louis.

Lev Gelb, WUSTL associate professor of chemistry, his graduate student Brian Barnes, and postdoctoral researcher Daniel Siderius, used computer simulations to study a very simple model of molecules on surfaces, which looks a lot like the computer game "Tetris." They have found that the shapes in this model (and in the game) do a number of surprising things.
WUSTL chemists headed by Lev Gelb simulated the motions and behavior of particles on a lattice and found "birds of a feather flock together." It's plainly evident that, in this four-component mixture of squares, rods, S shapes and Z shapes, the shapes all make little clusters, rather than completely mixing together. Tetris, anyone?
"First, different shapes don't mix very well with each other; each shape prefers to associate with others of the same kind," Gelb says. "When you put a lot of different shapes together, they separate from each other on microscopic scales, forming little clusters of nearly pure fluids. This is true even for the mirror-image shapes.
"Second, the structures of the pure (single-shape) fluids are quite complex and not what we might have predicted. There is a very strong tendency for some of the shapes, like rods and S- and Z- shapes, to align in the same direction. Finally, how `different looking' the shapes are isn't a good predictor for how well they mix; it turns out that the hard-to-predict characteristic structures of the fluids are more important than the shapes themselves, in this regard."
The researchers used Monte Carlo computer simulations of a simple lattice model (think of the lattice as a checkerboard), on which are placed "tetrominoes," which are S-, Z-, L-, J-, T-, rod- and square-shaped pieces.
Gelb and his colleagues use simulations to develop an atomic-scale understanding of the behavior of complex systems. They want to understand how molecules and nanoparticles of different shapes interact with each other to gain a better understanding of self-assembly, which is important in the development of new, strong materials for one, and designed catalysts for another.
Lining up
Gelb says that there has long been interest in self-assembly and in designing things that will assemble into predictable structures. Most researchers try to hold simple shapes together energetically, using some sort of chemical lock and key, such as DNA or hydrogen bonds. But if the particles have more shape to them, surprising things can happen.
"People have known for a long time when you make round nanoparticles and deposit them on a surface and you do it well, they make a nice, crystalline lattice," Gelb says. "If you do mixtures of two sizes you can get a number of different patterns with them. But if the particles aren't round, if they are short rods or things with more structure, it gets much more complicated quickly, and there's much less known about that."
The chemists also studied all 21 mixtures of two different shapes, as well as many combinations of three or more shapes.
"In all of the binary mixtures you get small-scale phase separation, which is counterintuitive," Gelb says. "It's not that the shapes repel each other. When there's no special repulsion between things or no stronger interaction between things of the same shape, you expect things to mix really well. In fact, that's not what happens."
Using ideas from classical thermodynamics and solution theory, the team was able to understand this separation using two different quantities. One is the virial coefficient, which measures the overlap between two shapes. They found that the shapes adopt alignments that minimize this overlap. Another is the volume of mixing. If you mix two liquids together, the volume of the mixture isn't necessarily the same as the volume of pure liquids you started with. In a mixture of water and ethanol, for instance, the volume of the mixture is smaller by about five percent than the sum of the original volumes. They found that in this model the volume always goes up when mixing different shapes.
Small world
"That's another indication that they don't mix well," Gelb says. "They take up more space when you mix them than when you allow them to be separate."
The model provides information on a very small world.
"If you think of the shapes as molecules sticking to a crystalline surface they would be a few Angstroms wide," says Barnes. "If you relate the model to nanoparticles, the shapes would be much larger, on the scale of tens of nanometers across."
In explaining the alignment phenomenon, Siderius offers the analogy of a roomful of people trying to circulate among each other.
"If they're all randomly placed, they'd bump shoulders frequently," he says. "But if they aligned a bit, everyone could move around more freely, which increases the entropy. In the past, we'd think of an ordered system as being low in entropy, but in this case the ordered state is high entropy."
Does it have anything to do with Tetris?
"Well, it suggests that one of the reasons the game is difficult is that the shapes don't fit together as well as we might think," says Gelb. "That, and they come down too fast."
The results were published in the on-line edition of the journal Langmuir on April 27, 2009
Journal reference:
Barnes et al. Structure, Thermodynamics, and Solubility in Tetromino Fluids. Langmuir, 2009; 090427084503036 DOI: 10.1021/la900196b
Adapted from materials provided by Washington University in St. Louis.

Carbon Nanotubes: Innovative Technology Or Risk To Health Or Environment?

SOURCE

ScienceDaily (May 10, 2009) — Carbon nanotubes have made a meteoric career in the past 15 years, even if their applications are still limited. Recent research results show that – apart from their favorable mechanical and electrical properties – they also have disadvantageous characteristics.

One aspect which has rarely been considered so far is now addressed by researchers of the research center Forschungszentrum Dresden-Rossendorf. “If the application of products and commodities containing carbon nanotubes will increase in the future, then there will be a higher probability for the tubes to get into the environment during their production, usage or disposal, to be distributed there, and to bind pollutants such as heavy metals on their way trough the environment”, says Harald Zaenker, scientist at the FZD.
Via water into the environment
An important way for carbon nanotubes of getting into the environment is the way via the water. In their original state, the flimsy carbon fibers with a diameter of less than 50 nanometers (1 nanometer = 1 millionth of a millimeter) are hardly water-soluble. At first glance, they should therefore not be mobile in groundwater, lakes etc., i.e. they should rapidly settle or deposit. However, carbon nanotubes are able to form colloidal solutions if their surface structure is changed. Changes in the surface structure can be brought about deliberately during the production of the tubes or can be induced by natural processes if the tubes are released into the environment.
A colloidal solution, unlike a true solution of water-soluble substances, is a solution in which the apparently dissolved substance is finely dispersed in the solvent forming tiny particles. These particles are still much bigger than the molecules of a dissolved substance in a true solution. As colloids, carbon nanotubes might be transported anywhere in environmental waters. It is known meanwhile that the tubes can even penetrate cell walls and, thus, might theoretically be able to enter also animal or human cells. In addition, changes in the surface structure of carbon nanotubes cause another effect: their capability to bind heavy metals is increased.
Tubes with changed surface
The scientists investigated carbon nanotubes both in their original state and in a state changed by oxidizing acids (such as a mixture of nitric and sulfuric acid). They found out that solutions of treated carbon nanotubes scatter light more strongly. “This is an indication that colloids have formed which do not settle”, Harald Zaenker says.
The researchers provided evidence for the first time that the heavy metal uranium, which is ubiquitous in the environment and, hence, also in the water, is particularly attached to the surface of treated carbon nanotubes. The scientists found out that the uranium uptake capacity is increased by an order of magnitude in comparison to untreated carbon nanotubes. “Therefore, it is plausible to assume that carbon nanotubes, if released to the environment, influence the transport of uranium in environmental waters and even in biological systems. The possible impact on the environment and on human health has in general been considered too little”, Harald Zaenker says.
On the other hand, the high bonding capacity of carbon nanotubes for uranium and other heavy metals also suggests using them for the removal of heavy metals from waters. However, they are not yet a cost-efficient alternative to classic water purifiers, Zaenker says. “Eventually, it is important to further study the behavior of carbon nanotubes in waters”, the scientist says. “Only then can the positive and negative aspects of carbon nanotubes be better assessed.”
Journal reference:
Schierz et al. Aqueous suspensions of carbon nanotubes: Surface oxidation, colloidal stability and uranium sorption. Environmental Pollution, 2009; 157 (4): 1088 DOI: 10.1016/j.envpol.2008.09.045
Adapted from materials provided by Forschungszentrum Dresden Rossendorf.

Nanowire Device Fabrication Moves Into High Gear

Source:

http://www.sciencedaily.com/releases/2007/10/071026162149.htm

ScienceDaily (Oct. 30, 2007) — In the growing catalog of nanoscale technologies, nanowires--tiny rows of conductor or semiconductor atoms--have attracted a great deal of interest for their potential to build unique atomic-scale electronics. But before you can buy some at your local Nano Depot, manufacturers will need efficient, reliable methods to build them in quantity. Researchers at the National Institute of Standards and Technology (NIST) believe they have one solution--a technique that allows them to selectively grow nanowires on sapphire wafers in specific positions and orientations accurately enough to attach contacts and layer other circuit elements, all with conventional lithography techniques.

Despite their name, nanowires are more than just electrical connectors. Researchers have used nanowires to create transistors like those used in memory devices and prototype sensors for gases or biomolecules. However working with objects only tens of nanometers wide is challenging. A common approach in the lab is to grow nanowires like blades of grass on a suitable substrate, mow them off and mix them in a fluid to transfer them to a test surface, using some method to give them a preferred orientation.
When the carrier fluid dries, the nanowires are left behind like tumbled jackstraws. Using scanning probe microscopy or similar tools, researchers hunt around for a convenient, isolated nanowire to work on, or place electrical contacts without knowing the exact positions of the nanowires. It's not a technique suitable for mass production.
Building on earlier work to grow nanowires horizontally on the surface of wafers (see "Gold Nano Anchors Put Nanowires in Their Place), NIST researchers used conventional semiconductor manufacturing techniques to deposit small amounts of gold in precise locations on a sapphire wafer. In a high-temperature process, the gold deposits bead up into nanodroplets that act as nucleation points for crystals of zinc oxide, a semiconductor.
A slight mismatch in the crystal structures of zinc oxide and sapphire induces the semiconductor to grow as a narrow nanowire in one particular direction across the wafer. Because the starting points and the growth direction are both well known, it is relatively straightforward to add electrical contacts and other features with additional lithography steps.
As proof of concept, the NIST researchers have used this procedure to create more than 600 nanowire-based transistors, a circuit element commonly used in digital memory chips, in a single process. In the prototype process, they report, the nanowires typical grew in small bunches of up to eight wires at a time, but finer control over the size of the initial gold deposits should make it possible to select the number of wires in each position. The technique, they say, should allow industrial-scale production of nanowire-based devices.
Reference: B. Nikoobakht. Toward industrial-scale fabrication of nanowire-based devices. Chem. Mater., ASAP Article 10.1021/cm071798p S0897-4756(07)01798-X. Web Release Date: October 9, 2007.
Adapted from materials provided by National Institute of Standards and Technology.

Fausto Intilla

www.oloscience.com

Three First-ever Atomic Nuclei Created; New Super-heavy Aluminum Isotopes May Exist

Source:

http://www.sciencedaily.com/releases/2007/10/071024130508.htm

ScienceDaily (Oct. 27, 2007) — Researchers at Michigan State University's National Superconducting Cyclotron Laboratory, NSCL, have created three never-before-observed isotopes of magnesium and aluminum. The results not only stake out new territory on the nuclear landscape, but also suggest that variants of everyday elements might exist that are heavier than current scientific models predict.

"It's been a longstanding project since the beginning of nuclear science to establish what isotopes can exist in nature," said Dave Morrissey, University Distinguished Professor of chemistry and one of the paper's authors. "This result suggests that the limit of stability of matter may be further out than previously expected; really, it shows how much mystery remains about atomic nuclei."
Particles that comprise atomic nuclei, protons and neutrons, are held together by the nuclear force. One of the four fundamental forces that collectively describe the interactions of all matter in the cosmos, the nuclear force, has been the subject of scientific inquiry since the 1930s.
Despite much progress in nuclear physics during the subsequent decades, understanding of how the nuclear force and other effects play out inside nuclei is far from complete. For example, even today scientists aren't sure exactly what combinations of protons and neutrons can make up most atomic nuclei.
One way experimental nuclear physicists explore this issue is by using accelerator facilities to create reactions that, in effect, kluge together piles of protons. An element is defined by its number of protons. For example, hydrogen has one proton; helium, two protons; oxygen eight protons, uranium, 92 protons. Whenever physicists establish a new proton limit, they invariably garner attention for conjuring new elements. In October 2006, a team of Russian and American scientists generated worldwide headlines for creating an element with 118 protons, the most protons ever recorded in a single nucleus.
Another way to probe nuclear stability is to see how many neutrons can be loaded onto nuclei of more quotidian elements, which is the focus of much of the work at NSCL. Elements can exist as different isotopes, which contain the same number of protons but different numbers of neutrons. As an example, the most abundant stable isotope of carbon has six protons and six neutrons. However, trace amounts of carbon-13 and carbon-14 -- with seven and eight neutrons respectively -- also can be found on Earth.
The neutron-limit, referred to as the neutron-dripline, is a basic property of matter. Yet remarkably, despite more than a half-century of inquiry, scientists know the dripline location only for the eight lightest elements, hydrogen to oxygen. So one very basic question -- what's the heaviest isotope of a given element that can exist" -- remains unanswered for all but eight of the hundred or so elements on the Periodic Table.
In an experiment that ran earlier this year at NSCL, researchers successfully created and detected three new super-heavy isotopes of magnesium and aluminum: magnesium-40, with 12 protons and 28 neutrons; aluminum-42, 13 protons and 29 neutrons; and aluminum-43, 13 protons and 30 neutrons. If the everyday version of aluminum were a 160-pound adult, aluminum-43 would be a muscular, 255-pound heavyweight.
"Evidence of particle stability for magnesium-40 obtained at NSCL is a major step in the field of rare isotope physics," said Hiro Sakurai, chief scientist at RIKEN in Japan, who was not involved in the research. The RIKEN research institute in Saitama, Japan, is home to the world's most powerful accelerator facility for creating radioisotope beams.
The fleeting appearance of these three nuclear newcomers is significant for several scientific and technical reasons.
First, when is comes to magnesium, the results indicate that the dripline extends at least as far as, and possibly beyond, magnesium-40. The isotope wasn't detected in several dripline-focused experiments conducted around the world since 1997 and the research community had begun to suspect that it was beyond the bounds of stability. Though it's difficult to compare across disciplines, physicists' success in detecting three magnesium-40 isotopes in the course of an 11-day experiment is roughly similar to the achievement of biologists who finally snap an image of an elusive and thought-to-be-extinct animal after years of traipsing through the jungle.
"The discovery of the hitherto unknown heaviest magnesium and aluminum isotopes at NSCL is a milestone in rare isotope research and is a great accomplishment for the worldwide scientific community exploring unstable nuclei close to the so-called neutron dripline," said Horst Stocker, director of Gesellschaft fur Schwerionenforschung, GSI, who was not involved in the research. Darmstadt, Germany-based GSI is one of the world's top accelerator facilities for producing heavy-ion beams for research.
Second, aside from being a similarly interesting outlier, aluminum-42 carries added importance since it is a near-dripline nucleus with an odd number of neutrons. Isotopes of lighter elements that toe the edge of existence generally have even numbers of neutrons due to the fact that neutrons naturally pair up inside nuclei. With an even number of neutrons, the nuclei in effect have a tidy, complete set of such pairs that collectively form a sort of energetic scaffolding that increases stability.
According to one of the leading theoretical models, aluminum-42 shouldn't exist. That it does suggests that the dripline may in fact tilt in the direction of more novel, neutron-rich isotopes, an implication that will help to extend nuclear theory and point the way to future experiments.
The NSCL result "alters the landscape of known nuclei, it alters our understanding of the forces that bind nuclei into stable objects, and it has important implications for future attempts with next-generation facilities to map the evolution of nuclear structure and existence into the most weakly bound nuclei," said Rick Casten, D. Allan Bromley Professor of Physics at Yale University, also not involved in the research.
The experimental technique itself also is noteworthy. Creating and measuring rare isotopes is always needle-in-a-haystack work that requires researchers to hunt for a few desired nuclei from a swarm of fast-moving and mostly known and therefore less interesting particles. But in this experiment, NSCL researchers achieved a hundred- to thousand-fold boost in their ability to filter out what can be thought of as junk. They did so by essentially jury-rigging the facility to filter the beam twice. The result was an ability to detect and measure isotopes so rare that they represent less than one in every million billion particles that passed by the detectors.
The dual filtering process, more properly known as two-stage separation, is a fixture in most new and planned facilities for rare isotope beam research, including the proposed upgrade of NSCL. This experiment marks one of the first uses of two-stage separation in the world and the first time the technique has been tried at NSCL, which typically filters and purifies particles only once in its A1900 separator.
NSCL detectors returned just one blip of data consistent with the existence of aluminum-43. This generally isn't enough to count as a discovery, according to the conventions of nuclear science. However, more than 20 instances of its immediate neighbor, aluminum-42, were observed. Because of this relative abundance and the fact that, due to pairing, the 30 neutrons in aluminum-43 should prove more stable than the 29 neutrons in aluminum-42, the solitary signature of aluminum-43 etched in the data logs carries more than usual amount of credibility.
"Experiments such as these are paving the way into the new era of nuclear structure studies that technological developments are opening to investigation for the first time ever," said Yale's Casten.
The findings appear in the October 25 issue of the journal Nature.
Adapted from materials provided by Michigan State University.

Fausto Intilla

www.oloscience.com

Novel Semiconductor Structure Bends Light 'Wrong' Way -- Exciting Application Potential

Source:

http://www.sciencedaily.com/releases/2007/10/071014163634.htm

Science Daily — A Princeton-led research team has created an easy-to-produce material from the stuff of computer chips that has the rare ability to bend light in the opposite direction from all naturally occurring materials. This startling property may contribute to significant advances in many areas, including high-speed communications, medical diagnostics and detection of terrorist threats.

The new substance is in a relatively new class of materials called "metamaterials," which are made out of traditional substances, such as metals or semiconductors, arranged in very small alternating patterns that modify their collective properties. This approach enables metamaterials to manipulate light in ways that cannot be accomplished by normal materials.
Previous metamaterials were two-dimensional arrangements of metals, which limited their usefulness. The Princeton invention is the first three-dimensional metamaterial constructed entirely from semiconductors, the principal ingredient of microchips and optoelectronics.
"To be useful in a variety of devices, metamaterials need to be three-dimensional," said Princeton electrical engineering professor Claire Gmachl, one of the researchers on the study. "Furthermore, this is made from semiconductors, which are extremely functional materials. These are the things from which true applications are made."
The research team, led by Princeton engineering graduate student Anthony Hoffman, will publish its findings online Oct. 14 in the journal Nature Materials. Other Princeton researchers on the team include graduate students Leonid Alekseyev, Scott Howard and Kale Franz; former Council of Science and Technology fellow Dan Wasserman, now at the University of Massachusetts-Lowell; and former electrical engineering professor Evgenii Narimanov, now at Purdue University. The team also includes collaborators from Oregon State University and telecommunications firm Alcatel-Lucent.
Light waves and other forms of electromagnetic radiation bend whenever they pass from one medium to another. This phenomenon, called refraction, is readily observable when a straw placed into a glass of water appears to be bent or broken. Lenses in reading glasses or a camera work because of refraction.
All materials have an index of refraction, which measures the degree and direction that light is bent as it passes through them. While materials found in nature have positive refractive indices, the material recently invented by Princeton researchers has a negative index of refraction.
In the case of the straw in a glass, normal water would make the underwater portion of the straw appear to bend toward the surface. If water were able to refract light negatively, as the newly invented semiconductor does, the segment of straw under the water would appear as if it were bending away from the surface
Far more than a neat optical illusion, negative refraction holds promise for the development of superior lenses. The positive refractive indices of normal materials necessitate the use of curved lenses, which inherently distort some of the light that passes through them, in telescopes and microscopes. Flat lenses made from materials that exhibit negative refraction could compensate for this aberration and enable far more powerful microscopes that can "see" things as small as molecules of DNA.
In addition, the Princeton metamaterial is capable of negative refraction of light in the mid-infrared region, which is used in a wide range of sensing and communications applications. Its unique composition results in less lost light than previous metamaterials, which were made of extremely small arrangements of metal wires and rings. The semiconductors that constitute the new material are grown from crystals using common manufacturing techniques, making it less complex, more reliable and easier to produce.
"Currently, the typical infrared lens is a massive object -- the setups are bulky," Hoffman said. "This new material may enable more compact mid-infrared optics because we now have a new material with an entirely new set of optical parameters in our toolkit."
The research is part of a multi-institutional research center called Mid-Infrared Technologies for Health and the Environment (MIRTHE). Researchers at MIRTHE are developing compact sensors that detect trace amounts of gases in the atmosphere and human breath. These could one day be used in devices that monitor air quality and enhance homeland security, as well as in non-invasive and on-the-spot medical tests for diabetes and lung disease.
The research relies on a new type of laser that emits mid-infrared light. Gmachl, who directs the MIRTHE project, said the new material could be used to make the lasers better and smaller.
Next, the team plans to incorporate the new metamaterial into lasers. Additionally, the researchers will continue to modify the material in attempts to make features ever smaller in an effort to expand the range of light wavelengths they are able to manipulate.
The work was supported by the MIRTHE center and the Princeton Center for Complex Materials (PCCM), both sponsored by the National Science Foundation.
Note: This story has been adapted from material provided by Princeton University, Engineering School.

Fausto Intilla

www.oloscience.com

New Path For Designing Novel Nanomaterials Discovered

Source:

http://www.sciencedaily.com/releases/2007/10/071012095246.htm

Science Daily — A University of Arkansas researcher and his colleagues have found a novel way to “look” at atomic orbitals, and have directly shown for the first time that they change substantially when interacting at the interface of a ferromagnet and a high-temperature superconductor.
This finding opens up a new way of designing nanoscale superconducting materials and fundamentally changes scientific convention, which suggests that only electron spin and atomic charge – not atomic orbitals – influence the properties of superconducting nanostructures. It also has implications for interfaces between other complex oxide materials.
Jacques Chakhalian, assistant professor of physics in the J. William Fulbright College of Arts and Sciences, and his colleagues will publish their findings online at the Science Express Web site, published by the journal Science, Oct. 11.
Until now, materials science researchers believed that an electron’s charge and spin influenced the characteristics of conventional bulk materials. Atomic orbitals, which consist of the patterns of electron density that may be formed in an atom, were previously thought to be inactive.
“In conventional materials like copper or silicon, you could account for everything you could see through charge and spin,” Chakhalian said. Further, orbitals have proved difficult to “see” through physical experimentation, so it wasn’t possible to examine any changes in orbital symmetry that might be taking place at the interface.
Chakhalian’s work has focused on what happens at the interface between two different materials – for instance, superconductors and ferromagnets, two materials with properties that were thought to be incompatible with each other in bulk. In 2006, he and his colleagues created the first high-quality material to have both superconducting and ferromagnetic properties, and they used that material in this experiment.
Chakhalian and his colleagues worked with synchrotron radiation at the Advanced Photon Source, Argonne National Laboratory in Argonne, Ill., to examine the interface between a high-temperature superconducting material containing copper oxide and a ferromagnetic material containing manganese oxide. The synchrotron light is electromagnetic radiation of varying wavelengths that can be tuned to a specific wavelength and polarization for a particular experiment. Unlike conventional X-rays, which diffuse through space, the synchrotron light beams are sharply focused, like a laser beam with extreme brilliance.
The researchers forced the two materials into unusual quantum states. Using a technique called resonant X-ray absorption, they were able to “look” at the atomic orbitals at the interface and determine their symmetry in a non-destructive way.
They found that the atomic orbitals changed the nature of their symmetry at the interface and created a covalent bond between the copper and manganese atoms. This bonding does not exist in the bulk of the individual materials
“When you merge these two materials, the atomic orbitals at the interface become important. They start contributing to the electronic properties of the material,” Chakhalian said. “This opens a new way of designing materials. We can design quantum materials with engineered physical properties.”
The discovery may allow researchers to manipulate nanoscale superconductivity at the interface – opening the possibility of creating room-temperature semiconductors.
Generators that use superconducting materials generate electricity extremely efficiently, at half the size of conventional generators. General Electric estimates the potential market for superconducting generators to be between $20 billion and $30 billion over the next decade.
Chakhalian’s colleagues include J.W. Freeland and M. van Veenendaal of the Advanced Photon Source, Argonne National Laboratory, Argonne, Ill.; and H.-U. Habermeier, G. Cristiani, G. Khaliullin and B. Keimer of the Max Planck Institute for Solid State Research in Stuttgart, Germany.
Note: This story has been adapted from material provided by University of Arkansas, Fayetteville.

Fausto Intilla
www.oloscience.com

Quantum Mechanics Predicts Unusual Lattice Dynamics Of Vanadium Metal Under Pressure

Source:

http://www.sciencedaily.com/releases/2007/10/071011125338.htm

Science Daily — A Swedish research team of Dr. Wei Luo & Professor Rajeev Ahuja and US team of Dr. Y. Ding & Prof. H.K. Mao have used theoretical calculations to understand a totally new type of high-pressure structural phase transition in Vanadium. This phase was not found in earlier experiments for any element and compound. These findings are being published in the Proceedings of the National Academy of Science.
The relation between electronic structure and the crystallographic atomic arrangement is one of the fundamental questions in physics, geophysics and chemistry. Since the discovery of the atomic nature of matter and its periodic structure, this has remained as one of the main questions regarding the very foundation of solid systems.
Scientists at Carnegie's Geophysical Laboratory, USA and Uppsala University, Sweden have discovered a new type of phase transition - a change from one form to another-in vanadium, a metal that is commonly added to steel to make it harder and more durable. Under extremely high pressures, pure vanadium crystals change their shape but do not take up less space as a result, unlike most other elements that undergo phase transitions. This work was appeared in the February 23, 2007 issue of Physical Review Letters.
Trying to understand why high-pressure vanadium uniquely has the record-high superconducting temperature of all known elements inspired us to study high-pressure structure of vanadium. Usually high superconductivity is directly linked to the lattice dynamics of material.
In present paper in PNAS, again a collaboration between Uppsala University and Carnegie's Geophysical Laboratory, USA, we have looked in to the lattice dynamics of vanadium metal and it shows a very unusual behavior under pressure.
A huge change in the electronic structure is driving force behind this unusual lattice dynamics. Moreover, our findings provide a new explanation for the continuous rising of superconducting temperature in high-pressure vanadium, and could lead us to the next breakthrough in superconducting materials.
Note: This story has been adapted from material provided by Uppsala University.

Fausto Intilla
www.oloscience.com

Light Shed On Light-emitting Nanodevice

Source:

http://www.sciencedaily.com/releases/2007/10/071008130207.htm

Science Daily — An interdisciplinary team of Cornell nanotechnology researchers has unraveled some of the fundamental physics of a material that holds promise for light-emitting, flexible semiconductors.
The discovery, which involved years of perfecting a technique for building a specific type of light-emitting device, is reported in the journal Nature Materials.*
The interdisciplinary team had long studied the molecular semiconductor ruthenium tris-bipyridine. For many reasons, including its ability to allow electrons and holes (spaces where electrons were before they moved) to pass through it easily, the material has the potential to be used for flexible light-emitting devices. Sensing, microscopy and flat-panel displays are among its possible applications.
The researchers set out to understand the fundamental physics of the material -- that is, what happens when it encounters an electric field, both at the interfaces and inside the film. By fabricating a device out of the ruthenium metal complex that was spin-coated onto an insulating substrate with pre-patterned gold electrodes, the scientists were able to use electron force microscopy to measure directly the electric field of the device.
A long-standing question, according to George G. Malliaras, associate professor of materials science and engineering, director of the Cornell NanoScale Science and Technology Facility and one of the co-principal investigators, was whether an electric field, when applied to the material, is concentrated at the interfaces or in the bulk of the film.
The researchers discovered that it was at the interfaces -- two gold metal electrodes sandwiching the ruthenium complex film -- which was a huge step forward in knowing how to build and engineer future devices.
"So when you apply the electric field, ions in the material move about, and that creates the electric fields at the interfaces," Malliaras explained.
Essential to the effort was the ability to pattern the ruthenium complex using photolithography, a technique not normally used with such materials and one that took the researchers more than three years to perfect, using the knowledge of experts in nanofabrication, materials and chemistry.
The patterning worked by laying down a gold electrode and a polymer called parylene. By depositing the ruthenium complex on top of the parylene layer and filling in an etched gap between the gold electrodes, the researchers were then able to peel the parylene material off mechanically, leaving a perfect device.
Ruthenium tris-bipyridine has energy levels well suited for efficient light emission of about 600 nanometers, said Héctor D. Abruña, the E.M. Chamot Professor of Chemistry, and a principal co-investigator. The material, which has interested scientists for many years, is ideal for its stability in multiple states of oxidation, which, in turn, allows it to serve as a good electron and hole transporter. This means that a single-layer device can be made, simplifying the manufacturing process.
"It's not fabulous, but it has a reasonable emission efficiency," Abruña said. "One of the drawbacks is it has certain instabilities, but we have managed to mitigate most of them."
Among the other authors were co-principal investigators Harold G. Craighead, the C.W. Lake Jr. Professor of Engineering, and John A. Marohn, associate professor of chemistry and chemical biology.
*September 30
Note: This story has been adapted from material provided by Cornell University.

Fausto Intilla
www.oloscience.com

Unveiling The Structure Of Microcrystals

Source:

http://www.sciencedaily.com/releases/2007/10/071004092126.htm

Science Daily — Microcrystals take the form of tiny grains, so small that they resemble a powder. How can we determine their structure?
Until now, the technique of X-ray diffraction, normally used to study crystals, was not an appropriate solution. For the first time, researchers from the ESRF and the CNRS have used X-ray diffraction to determine the structure of microcrystal grains of only one cubic micrometre in size.
They gained a factor of a thousand on the size of the analysable samples thanks to new equipment created at the ESRF. This breakthrough opens up new possibilities of research to chemists, physicists and biologists.
The properties of a crystal are determined by the arrangement of its atom in space, its crystalline structure. Scientists use X-ray or neutron diffraction to study crystalline structure when the size of the crystal is more than 10 cubic micrometres. Below this limit, the solid material is considered a powder.
Scientists can apply powder diffraction to analyse such a material but this technique is not easy to exploit. Moreover, powder diffraction can only be used for materials with grain sizes of less than three millionths of a cubic micrometre. Due to these limitations, a determination of the structure of new synthetic solids in powder form is not always possible because the crystals are too small.
The teams from the ESRF and the Institute Lavoisier (CNRS/Université de Versailles Saint-Quentin) have used new set-up permitting X-ray diffraction on crystals of a size of one cubic micrometre, a volume a thousand times smaller than that ever attainable before. This new set-up consists of a focusing system for the ESRF beam, coupled with a goniometer, an instrument to position the sample with maximum precision.
The researchers studied the structure of an organic-inorganic hybrid compound (a microporous aluminium carboxylate), which could be used for gas absorption or to encapsulate various organic molecules. This study confirms that the new set-up allows pushing back the limits in crystal dimension accessible to X-ray diffraction.
“It is a revolution: what was considered a powder in the past has become a crystal today. Researchers can now bring forward samples left in their cupboards because the sizes had previously prevented their study. Now they will be able to elucidate the structures of these samples, with potentially great scientific advances on the horizon”, explains Thierry Loiseau, from the Institut Lavoisier.
Reference: A Microdiffraction Set-up for Nanoporous Metal-Organic-Framework-Type Solids. C. Volkringer, D. Popov, T. Loiseau, N. Guillou, G. Férey, M. Haouas, F. Taulelle, C. Mellot-Draznieks, M. Burghammer and C. Riekel, Nature Materials, 6 (2007) 760-4.
Note: This story has been adapted from material provided by European Synchrotron Radiation Facility.

Fausto Intilla
www.oloscience.com

New Giant Molecule Created

Source:

http://www.sciencedaily.com/releases/2007/10/071005214924.htm

Science Daily — Ulrich Kortz, Professor of Chemistry at Jacobs University, and his team successfully synthesized a polyoxometalate with 100 Tungsten and 20 Cerium atoms that has a molar mass of about 30 kilo Dalton. With a maximum diameter of 4.2 nm the inorganic molecule is comparable in size to large complex bio-molecules or even small viruses.

Polyoxometalates are anionic metal-oxygen clusters of large structural diversity with chemical properties, which make them especially interesting for applications in catalysis, but also in materials science and nanotechnology.
Ulrich Kortz and his co-workers now achieved the synthesis of the tungstogermanate*, which belongs to the polyoxometalates, by condensation of the precursors [α-GeW9O34]10- and Cerium(III) ions in aqueous solution.
With about 600 atoms in total, amongst them 100 atoms of the heavy metal Tungsten, the new compound is the third largest molecular polytungstate ever synthesized. In addition it contains the largest number of atoms of the Rare Earth Cerium ever incorporated in such a compound.
„A single molecule of our new giant tungstate has many catalytically active centers and therefore a very high catalytic potential, which normally applies only to biological catalyst molecules. Being a lot less temperature and oxidatively sensitive than bio-catalysts though and in crystalline form applicable as a heterogenic solid catalyst in liquid phase reactions our new tungstogermanate is predestined for industrial purposes,“ says Ulrich Kortz about the possible applications of the newly created molecule.
“In addition our successful synthesis allows very good inferences about the mechanism of formation by stepwise self-assembly of the simple precursors in a classic one-pot synthesis, which is vitally important for the development of other so-called ‘molecular machines’, large molecules designed to have very specific functions,“ the Jacobs chemist concludes.
*Tungstogermanate [Ce20Ge10W100O376(OH)4(H2O)30]56-
The reaction conditions and the molecular structure were published in Angewandte Chemie (doi: 10.1002/anie.200701422).
Note: This story has been adapted from material provided by Jacobs University.

Fausto Intilla

www.oloscience.com

What Makes Quantum Dots Blink?

Source:

http://www.sciencedaily.com/releases/2007/10/071004165602.htm

Science Daily — In order to learn more about the origins of quantum dot blinking, researchers from the U.S. Department of Energy's Argonne National Laboratory, the University of Chicago and the California Institute of Technology have developed a method to characterize it on faster time scales than have previously been accessed.

Nanocrystals of semiconductor material, also known as quantum dots, are being intensively investigated for applications such as light-emitting diodes, solid-state lighting, lasers, and solar cells. They are also already being applied as fluorescent labels for biological imaging, providing several advantages over the molecular dyes typically used, including a wider range of emitted colors and much greater stability.
Quantum dots have great promise as light-emitting materials, because the wavelength, or color, of light that the quantum dots give off can be very widely tuned simply by changing the size of the nanoparticles. If a single dot is observed under a microscope, it can be seen to randomly switch between bright and dark states.
This flickering, or blinking, behavior has been widely studied, and it has been found that a single dot can blink off for times that can vary between microseconds and several minutes. The causes of the blinking, though, remain the subject of intense study.
The methods developed by Matt Pelton of Argonne's Center for Nanoscale Materials and his team of collaborators has revealed a previously unobserved change in the blinking behavior on time scales less than a few microseconds. This observation is consistent with the predictions of a model for quantum-dot blinking previously developed by Nobel Laureate Rudolph Marcus, contributor to this research, and his co-workers. In this model, the blinking is controlled by the random fluctuation of energy levels in the quantum dot relative to the energies of trap states on the surface of the nanocrystal or in the nearby environment.
The results of this research provide new insight into the mechanism of quantum-dot blinking, and should help in the development of methods to control and suppress blinking. Detailed results of this work have been published in a paper in the Proceedings of the National Academy of Sciences.
Argonne's Center for Nanoscale Materials work for this research was funded by the U.S. Department of Energy's Office of Basic Energy Science.
Note: This story has been adapted from material provided by DOE/Argonne National Laboratory.

Fausto Intilla

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